Tetrahedron Letters p. 2825 - 2828 (1987)
Update date:2022-08-11
Topics:
Hawkins, Joel M.
Sharpless, K. Barry
Titanium(IV)-pyridinediol complex 5 was studied as a model for titanium-tartarate asymmetric epoxidation catalysts.The sign of induction depended on the alkyl group of the alkyl hydroperoxide oxidant.Trityl hydroperoxide gave 64percent ee in the direction predicted by the model.
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