Synthesis of a Phospha-arsene and a Phosphastibene; the First Compounds with Phosphorus-Arsenic and Phosphorus-Antimony Double Bonds

DOI: 10.1039/c39830000881

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 881 - 882 (1983)

Update date:2022-08-11

Topics:

Authors:

Cowley, Alan H.

Lasch, Jon G.

Norman, Nicholas C.

Pakulski, Marek

Whittlesey, Bruce R.

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Article abstract of DOI:10.1039/c39830000881

The reaction of (Me3Si)2CHMCl2 (M = As or Sb) with (2,4,6-Bu^t3C6H2)PH2 in the presence of 1,5-diazabicyclo<5.4.0>undec-5-ene affords the double-bonded compounds, (2,4,6-Bu^t3C6H2)P=MCH(SiMe3)2 (M = As or Sb).

Full text of DOI:10.1039/c39830000881

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