Synthesis of heterocyclic molybdenum carbene complexes using haloalkyl-substituted epoxides

DOI: 10.1016/0022-328X(95)05503-H

Source and publish data:

Journal of Organometallic Chemistry p. C12 - C14 (1995)

Update date:2022-08-17

Topics:

Authors:

Adams, Harry

Bailey, Neil A.

Marson, Charles M.

Randall, Linda

Winter, Mark J.

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Article abstract of DOI:10.1016/0022-328X(95)05503-H

The reaction of and an excess of LiI with ^- gives crystallographically characterized .This reacts with C5H5NO to give a high yield of the γ-lactam .The corresponding reaction of with excess LiI and ^- gives (also crystallographically characterized) rather than a carbene complex.Keywords: Molybdenum; Carbene; Epoxides; Group 6; Isocyanide; Heterocycle

Full text of DOI:10.1016/0022-328X(95)05503-H

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