Journal of Organic Chemistry p. 1676 - 1678 (1984)
Update date:2022-08-16
Topics: Rearrangement Formation of Azidoalkene Reaction with Quinone Nitrene Formation
Schultz, Arthur G.
McMahon, Wayne G.
Rearrangements of 2-(azidopropyl)-1,4-benzo- and -1,4-naphthoquinones give 2-(2-Δ1-pyrrolinyl)-4-cyclopentene-1,3-diones and pyrrolidino<2,1-b>azepine-1,5-diones via intermediate triazolines.Acid-catalyzed triazoline isomerization to an isolable diazo enedione is reported.
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Doi:10.1016/0022-328X(84)80163-1
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