Synthesis and Structure of Sulphur Derivatives of a Methylenephosphine

DOI: 10.1039/c39840000698

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 698 - 699 (1984)

Update date:2022-08-15

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Authors:

Caira, Mino

Neilson, Robert H.

Watson, William H.

Wisian-Neilson, Patty

Xie, Ze-Min

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Article abstract of DOI:10.1039/c39840000698

The methylenephosphine MesP=C(SiMe3)2 <(1) Mes = mesityl> is smoothly oxidized by elemental sulphur to the 3-membered ring system Mes-cyclo(SiMe3)2, (3), which, upon treatment with Buⁿ3P, is converted into the 3-co-ordinate phosphorane MesP(=S)=C(SiMe3)2, (2); the nearly isostructural nature of compounds (2) and (3) is confirmed by their X-ray crystallographic analyses.

Full text of DOI:10.1039/c39840000698

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