Tetrahedron Letters p. 4133 - 4136 (1984)
Update date:2022-08-29
Topics:
Ohfune, Yasufumi
Nishio, Hideki
Allylic oxidation of (2S)-N-t-butoxycarbonyl-2-amino-4-pentenoic acid methyl ester afforded, stereoselectively, a (2S,3R)-2-amino-3-hydroxyl derivative, which was converted to the unusual amino acid (-)-detoxinine via a chelation controlled aldol condensation followed by a pyrrolidine ring formation.
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(1985)
