Tetrahedron p. 4671 - 4684 (1986)
Update date:2022-08-11
Topics:
Neckers, D. C.
Paczkowski, Jerzy
We define a microheterogeneous photo-oxidation to be a photosensitized oxidation reaction whose efficiency is enhanced beyond that of diffusion control by the covalent bonding of a sensitizer to a ligand.The ligand is responsible for enhancing the local concentration of a specific substrate susceptible to reaction with an excited state derived from the proximate sensitizer.We illustrate the principle with several applications in singlet oxygen processes.
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