Regioselectivity of dechlorination: reductive dechlorination of polychlorobiphenyls by polymethylhydrosiloxane-alkali metal

DOI: 10.1016/0022-328X(92)83434-J

Source and publish data:

Journal of Organometallic Chemistry p. 91 - 98 (1992)

Update date:2022-08-29

Topics:: Authors:

Hawari, Jalal

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Article abstract of DOI:10.1016/0022-328X(92)83434-J

Polychlorobiphenyls are completely dechlorinated to biphenyl by a polymethylhydrosiloxane-alkali metal system at ambient conditions.Dechlorination proceeded via the formation of a polychlorobiphenyl radical anion, which cleaved with a regioselectivity similar to that normally observed in nucleophilic substitution of polyhaloarenes.

Full text of DOI:10.1016/0022-328X(92)83434-J

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Regioselectivity of dechlorination: reductive dechlorination of polychlorobiphenyls by polymethylhydrosiloxane-alkali metal

DOI: 10.1016/0022-328X(92)83434-J

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(92)83434-J

Full text of DOI:10.1016/0022-328X(92)83434-J

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