Journal of Organometallic Chemistry p. 91 - 98 (1992)
Update date:2022-08-29
Topics:
Hawari, Jalal
Polychlorobiphenyls are completely dechlorinated to biphenyl by a polymethylhydrosiloxane-alkali metal system at ambient conditions.Dechlorination proceeded via the formation of a polychlorobiphenyl radical anion, which cleaved with a regioselectivity similar to that normally observed in nucleophilic substitution of polyhaloarenes.
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