Regioselectivity of dechlorination: reductive dechlorination of polychlorobiphenyls by polymethylhydrosiloxane-alkali metal

DOI: 10.1016/0022-328X(92)83434-J

Source and publish data:

Journal of Organometallic Chemistry p. 91 - 98 (1992)

Update date:2022-08-29

Topics:: Authors:

Hawari, Jalal

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(92)83434-J

Polychlorobiphenyls are completely dechlorinated to biphenyl by a polymethylhydrosiloxane-alkali metal system at ambient conditions.Dechlorination proceeded via the formation of a polychlorobiphenyl radical anion, which cleaved with a regioselectivity similar to that normally observed in nucleophilic substitution of polyhaloarenes.

Full text of DOI:10.1016/0022-328X(92)83434-J

Products guided by the article

Product name:1,1'-Biphenyl

Cas No:92-52-4

R&D Labs maybe for 92-52-4

ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road

Relevant to this article

Synthesis, crystal structure, and DNA-binding of a 3-D netlike supramolecular manganese picrate complex with 2,6-bis(benzimidazol-2-yl)pyridine

Doi:10.1080/00958971003728288
(2010)
A Highly Regioselective Palladium-Catalyzed O,S Rearrangement of Cyclic Thiocarbonates

Doi:10.1002/ejoc.201701181
(2017)
Doi:10.1063/1.1743237
(1957)
Stuffed Methyltransferase Catalyzes the Penultimate Step of Pyochelin Biosynthesis

Doi:10.1021/acs.biochem.8b00716
(2019)
A highly regio- and stereo-selective [3+2] annulation of allylic compounds and 2-substituted 1,1-dicyanoalkenes through a catalytic carbon-phosphorus ylide reaction

Doi:10.1016/j.tet.2007.02.115
(2007)
Emerging Cubic Chirality in γCD-MOF for Fabricating Circularly Polarized Luminescent Crystalline Materials and the Size Effect

Doi:10.1002/anie.202000589
(2020)

Article Doi

Regioselectivity of dechlorination: reductive dechlorination of polychlorobiphenyls by polymethylhydrosiloxane-alkali metal

DOI: 10.1016/0022-328X(92)83434-J

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(92)83434-J

Full text of DOI:10.1016/0022-328X(92)83434-J

Products guided by the article

R&D Labs maybe for 92-52-4

Relevant to this article

Hot Product