Monomeric Alkoxo Complexes of Copper(I): Syntheses and Structures of Di(p-tolylisocyanide)(2,6-di-t-butylphenoxo)copper(I) and a Di(2,6-dimethylphenoxo)cuprate(I)

DOI: 10.1039/c39840000888

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 888 - 890 (1984)

Update date:2022-08-17

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Authors:

Fiaschi, Paolo

Floriani, Carlo

Pasquali, Marco

Chiesi-Villa, Angiola

Guastini, Carlo

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Article abstract of DOI:10.1039/c39840000888

Copper(I) chloride reacts with 2,6-Bu^t2C6H3ONa in the presence of p-MeC6H4NC to give <(p-MeC6H4NC)2Cu(2,6-Bu^t2C6H3O)> containing a tri-coordinated copper(I) atom , while the solution obtained from 'CuCOCl' and 2,6-Me2C6H3ONa reacts with PhCH=N-CH2CH2-N=CHPh, BEN, to give the diphenoxocuprate(I) +<(2,6-Me2C6H3O)2Cu>- .

Full text of DOI:10.1039/c39840000888

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