Journal of the American Chemical Society p. 4721 - 4724 (1985)
Update date:2022-09-26
Topics:
Hawari, J. A.
Davis, S.
Engel, P. S.
Gilbert, B. C.
Griller, D.
Product studies and kinetic electron paramagnetic resonance methods were used to investigate the free radical reaction between alkanes and carbon tetrachloride in solution.Trichloromethyl radicals abstracted hydrogen from simple alkanes with rate constants of ca. 60 M-1 s-1 at 300 K. in good agreement with gas-phase data.However, rate constants for chlorine abstraction by alkyl radicals from carbon tetrachloride were ca.E4 M-1 s-1 and were therefore ca. 2 orders of magnitude higher in solution than in the gas phase.Possibilities for the origin of this effect are discussed.
View MoreShandong Loyal Chemical industrial Co.,Ltd
Contact:0533-7451788
Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Kaymossy BioChem Tech Co., Ltd
website:http://www.kaimosi.com
Contact:0571-87191913/0571-87199097
Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)
Contact:+86-027-84466317 __ +86-15387123698
Address:wuhan - china
website:http://www.chinabarton.com
Contact:+86-573-82719618
Address:No. 162 Fumin Road, Honghe Town,
Shanghai Hanshare Industry Co.,Ltd.
Contact:86 21 20960688
Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Doi:10.1002/macp.1976.021770317
(1976)Doi:10.1021/ja01097a037
(1953)Doi:10.1016/S0040-4020(03)00903-7
(2003)Doi:10.1007/BF00742459
()Doi:10.1016/S0040-4039(03)01383-2
(2003)Doi:10.1021/ja00402a078
(1981)
