Tetrahedron Letters p. 951 - 954 (1986)
Update date:2022-08-17
Topics:
Mishima, Masaaki
Fujio, Mizue
Tsuno, Yuho
The gas phase basicities of m,p-substituted methyl benzoates have been determined by means of the pulsed ICR mass spectrometer.LArSR analysis of the substituent effect provides a smaller r+ of 0.45 compared to that of acetophenone basicities, indicating a reduced resonance demand of the conjugate acid ion of methyl benzoate.
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