Acid-catalysed Additions of Acetylenes to (X=Cl, Br, or I) to give Dimetallated Olefin Complexes of Type (R=H, Ph, or C6H4Me-p)

DOI: 10.1039/DT9880000457

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 457 - 460 (1988)

Update date:2022-08-17

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Authors:

Higgins, Simon J.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9880000457

The addition of acetylenes to (dppm=Ph2PCH2PPh2; X=Cl, Br, or I) is catalysed by traces of acid and (in some cases) methanol, giving (R=H, Ph, or C6H4Me-p) containig the dipalladated olefin ligand HC=CR.These r

Full text of DOI:10.1039/DT9880000457

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