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Cas Database

Name	Furfuryl acetate	EINECS	210-775-9
CAS No.	623-17-6	Density	1.12 g/cm³
PSA	39.44000	LogP	1.34270
Solubility	0.5-1.0 g/100 mL at 23 °C in water	Melting Point	N/A
Formula	C₇H₈O₃	Boiling Point	177 °C at 760 mmHg
Molecular Weight	140.139	Flash Point	65.6 °C
Transport Information	N/A	Appearance	Colorless to light yellow liquid
Safety	24/25-37/39-26	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	2-Furanmethanol acetate;2-Furylcarbinyl acetate;Furfuryl alcohol, acetate;5-17-03-00344 (Beilstein Handbook Reference);Acetic acid furfurylester;2-Acetoxymethylfuran;2-Furfuryl acetate;2-Furanmethanol, acetate;2-Furanmethyl acetate;FEMA No. 2490;Acetic acid furfuryl ester;2-furylmethyl acetate;	Article Data	52

Furfuryl acetate Synthetic route

: 623-17-6
furfurylacetate

: 93-55-0
1-phenyl-propan-1-one

: 1440662-73-6
(E)-(5-(3-oxo-3-phenylprop-1-enyl)furan-2-yl)methyl acetate

Conditions

Conditions	Yield
With silver (II) carbonate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; lithium acetate; palladium diacetate; tricyclohexylphosphine In 1,2-dimethoxyethane at 100℃; for 24h; Schlenk technique; Inert atmosphere;	56%

: 623-17-6
furfurylacetate

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With lipase B from Candida antarctica immobilized on Immobead 150 In aq. phosphate buffer at 40℃; for 0.333333h; pH=7.4;	89%
With methanol; potassium permanganate; trimethylsulphonium iodide at 25℃; under 760.051 Torr; chemoselective reaction;	80%
With methanol; potassium permanganate at 25℃; chemoselective reaction;	78%
With [t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h; Deacetylation;	82 % Chromat.
[t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h;	82 % Chromat.

: 623-17-6
furfurylacetate

: 576-26-1
2.6-dimethylphenol

: 4-(furan-2-ylmethyl)-2,6-dimethylphenol

Conditions

Conditions	Yield
With Montmorillonite In dichloromethane at 60℃; Sealed tube;	35%

: 108-31-6
maleic anhydride

: 623-17-6
furfurylacetate

: 6331-95-9, 19308-92-0
(+/-)-(1RS,2SR,6RS,7SR)-(3,5-dioxo-4,10-dioxatricyclo[5.2.1.02,6]dec-8-en-1-yl)methyl acetate

Conditions

Conditions	Yield
In toluene at 23℃;	86%
In toluene at 23℃; for 97h; Diels-Alder reaction;	74%
In diethyl ether at 25℃; for 168h; Diels-Alder cycloaddition;	34%
With diethyl ether

: 623-17-6
furfurylacetate

: 100-66-3
methoxybenzene

2<(4-Methoxylphenyl)methyl>furan: 2<(4-Methoxylphenyl)methyl>furan

Conditions

Conditions	Yield
With bis(trifluoromethanesulfonyl)amide In dichloromethane at 20℃; for 0.333333h;	70 %Chromat.

: 623-17-6
furfurylacetate

A: 111-29-5
1 ,5-pentanediol

B: 5343-92-0
1,2-pentanediol

C pentan-1-ol: pentan-1-ol

Conditions

Conditions	Yield
Stage #1: furfurylacetate With 5%-palladium/activated carbon; hydrogen; acetic acid at 100℃; under 7600.51 Torr; for 6h; Autoclave; Stage #2: With methanol; water Reagent/catalyst; Temperature; Pressure; Reflux;	A 24% B 15% C 56%

: 623-17-6
furfurylacetate

methyl phosphite: methyl phosphite

acetic acid 5-(dimethoxy-phosphoryl)-furan-2-ylmethyl ester: acetic acid 5-(dimethoxy-phosphoryl)-furan-2-ylmethyl ester

Conditions

Conditions	Yield
With manganese triacetate In acetic acid at 80℃; for 3h;	86%

: 623-17-6
furfurylacetate

bis(pinacol)diborane: bis(pinacol)diborane

: (CH3)4C2O2BCH2C4H3O

Conditions

Conditions	Yield
With gold-nanoparticles supported on TiO2 In 1,4-dioxane at 60℃; for 2h;	53%

: 623-17-6
furfurylacetate

: 118-92-3
anthranilic acid

: 117078-27-0
1-acetoxymethyl-11-oxatricyclo[6.2.1.02,7]undeca-2,4,6,9-tetraene

Conditions

Conditions	Yield
Stage #1: anthranilic acid With isopentyl nitrite; trichloroacetic acid In tetrahydrofuran at 0 - 20℃; Stage #2: furfurylacetate With methyloxirane In tetrahydrofuran Heating; Further stages.;	75%
With isopentyl nitrite In 1,2-dimethoxyethane	45.8%

: 623-17-6
furfurylacetate

: 137073-16-6
3-tert-butyl-3-methylcycloprop-1-ene

: 1268380-58-0
(3E,5E,7E)-8,9,9-trimethyl-2-oxodeca-3,5,7-trienyl acetate

Conditions

Conditions	Yield
Stage #1: furfurylacetate; 3-tert-butyl-3-methylcycloprop-1-ene With C16H26AuNP(1+)*F6Sb(1-) In dichloromethane at 25℃; for 0.25h; Inert atmosphere; Stage #2: With iodine In dichloromethane for 1h; Inert atmosphere;	78%

Furfuryl acetate Chemical Properties

Molecular Formula: C₇H₈O₃

Formula Weight: 140.14
bp of 2-FURANMETHYL ACETATE (623-17-6): 175-177 ^°C(lit.)
density : 1.118 g/mL at 25 ^°C(lit.)
refractive index : n20/D 1.462(lit.)
Fp of 2-FURANMETHYL ACETATE (623-17-6): 150 ^°F
Water Solubility : 0.5-1.0 g/100 mL at 23 ^oC
PHYSICAL STATE: Clear to pale yellow liquid

Furfuryl acetate Uses

2-FURANMETHYL ACETATE (623-17-6) is used as a solvent and flavor enhancer and modifier in foods and perfumes. Also it is used as intermediate of dyes, resins and spices.

Furfuryl acetate Production

2-FURANMETHYL ACETATE (623-17-6) is derived from furan reaction with acetic anhydride.

Furfuryl acetate Toxicity Data With Reference

1.		mmo-sat 1 mg/plate		ENMUDM Environmental Mutagenesis. 8 (Suppl 7)(1986),1.
2.		mma-sat 2500 µg/plate		ENMUDM Environmental Mutagenesis. 8 (Suppl 7)(1986),1.

Furfuryl acetate Consensus Reports

Reported in EPA TSCA Inventory.

Furfuryl acetate Safety Profile

Safety: CAUTION: May irritate eyes, skin, and respiratory tract
Hazard Codes : Xi (Irritant)
Risk Statements : 36/37/38 (Irritating to eyes, respiratory system and skin)
Safety Statements : 24/25-37/39-26 (Avoid contact with skin and eyes; Wear suitable gloves and eye/face protection; In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
WGK Germany : 3
RTECS : LU9120000
Hazard Note : Irritant
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.

Furfuryl acetate Standards and Recommendations

ASSAY: 98.0% min
ACIDITY: 0.1% max

Furfuryl acetate Specification

Storage: Protect from moisture. Store in tightly sealed containers in a cool place.

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