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98-00-0

Basic Information
CAS No.: 98-00-0
Name: Furfuryl alcohol
Molecular Structure:
Molecular Structure of 98-00-0 (Furfuryl alcohol)
Formula: C5H6O2
Molecular Weight: 98.11
Synonyms: 2-Furylcarbinol;alpha-Furylcarbinol;2-(Hydroxymethyl)furan;Furylcarbinol (VAN);Furfurylcarb;1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H;Methanol, (2-furyl)-;2-Furfurylalkohol;5-17-03-00338 (Beilstein Handbook Reference);Furfuryl alcohol [UN2874] [Poison];.alpha.-Furylcarbinol;.alpha.-Furfuryl alcohol;2-Furanylmethanol;2-Furylmethanol;2-Furanmethanol;2-Furfuryl alcohol;Furfuralcohol;Furfurylalkohol;Furan-2-methanol;Furfurol (2-Furfuryl alcohol);Furylcarbinol;NCI-C56224;Furfuranol;2-Furfurylalkohol [Czech];FEMA No. 2491;
EINECS: 202-626-1
Density: 1.14 g/cm3
Melting Point: -29 °C
Boiling Point: 169.999 °C at 760 mmHg
Flash Point: 65 °C
Solubility: miscible with water
Appearance: clear yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 20/21/22
Safety: 23-36/37/39
Transport Information: UN 2874 6.1/PG 3
PSA: 33.37000
LogP: 0.77190
Synthetic route
98-01-1

furfural

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With Pt(3)Co(3)/C; hydrogen In water at 35℃; under 750.075 Torr; for 10h; Reagent/catalyst; Pressure; Temperature; Solvent; Concentration;100%
With HRO/TiO2; hydrogen In water at 150℃; under 15001.5 Torr; for 3h;100%
With hydrogen In isopropyl alcohol at 179.84℃; under 22502.3 Torr; for 1.25h; Reagent/catalyst;100%

C20H20BO8(1-)*Na(1+)

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With water100%
98-01-1

furfural

A

98-00-0

(2-furyl)methyl alcohol

B

88-14-2

2-furanoic acid

Conditions
ConditionsYield
Stage #1: furfural With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry;
Stage #2: With hydrogenchloride In water for 0.0833333h; Green chemistry;
A 99%
B 99%
With TEA; magnesium bromide In dichloromethane at 20℃; for 48h; Cannizzaro reaction;A 90%
B n/a
With sodium hydroxide In water at 0 - 20℃; for 12h; Reagent/catalyst; Cannizzaro Reaction;A 88%
B 83%
611-13-2

2-furoic acid methyl ester

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With ethanol; [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) at 100℃; for 24h; Inert atmosphere; Sealed tube; Darkness;99%
With C13H34BFeNOP2; hydrogen In tetrahydrofuran at 100℃; under 22502.3 Torr; for 18h; Autoclave; Inert atmosphere;95%
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In toluene at 80℃; under 37503.8 Torr; for 10h;80%
67-47-0

5-hydroxymethyl-2-furfuraldehyde

14694-95-2

Wilkinson's catalyst

A

98-00-0

(2-furyl)methyl alcohol

B

15318-33-9, 16353-77-8, 13938-94-8

chlorocarbonylbis(triphenylphosphine)rhodium(I)

Conditions
ConditionsYield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;A 99%
B n/a
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 2h at 70°C; detn. of products by GC;A 48%
B n/a
65148-89-2

2-(furan-2-ylmethoxy)tetrahydro-2H-pyran

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With chloral hydrate In hexane at 0 - 5℃; for 0.5h; Inert atmosphere;98%
With methanol; Montmorillonite K-10 clay at 20℃; Methanolytic deprotection;95%
With zinc tetrafluoroborate In methanol; dichloromethane; water at 20℃; for 0.75h;92%
614-99-3

Ethyl 2-furoate

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 5h; Glovebox; Autoclave;97%
With ethanol; ruthenium(bis[2‐(ethylsulfanyl)ethyl]amine)(dichloro)(triphenylphosphine); potassium tert-butylate In toluene at 80℃; for 16h;95%
With ethylmagnesium bromide; poly(methylhydrosiloxane); bis(cyclopentadienyl)titanium dichloride In tetrahydrofuran; diethyl ether for 17.5h; Ambient temperature;89%
98-01-1

furfural

62-53-3

aniline

A

98-00-0

(2-furyl)methyl alcohol

B

4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
Stage #1: furfural; aniline at 25℃; for 0.166667h;
Stage #2: With sodium tetrahydroborate; toluene-4-sulfonic acid at 25℃; for 0.166667h;
A n/a
B 97%
With hydrogen; edetate disodium; iron(II) sulfate In water at 150℃; under 20686.5 Torr; for 12h; Title compound not separated from byproducts.;A 7 % Chromat.
B 72 % Chromat.
Stage #1: furfural at 40℃; for 0.166667h;
Stage #2: aniline With sodium tetrahydroborate at 40℃; for 3h;
Stage #3: With methanol at 0℃; for 0.5h; chemoselective reaction;
121389-55-7

tert-butyl(furan-2-ylmethoxy)dimethylsilane

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With Decaborane In methanol at 20℃; for 0.5h;96%
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 25℃; for 8h;93%
With acetyl chloride In methanol at 20℃; for 0.583333h;85%
With tin(ll) chloride In water for 5h; Heating;85%
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.166667h;83%
67-47-0

5-hydroxymethyl-2-furfuraldehyde

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With palladium nanoparticles deposited on porous SBA-15 In cyclohexane at 130℃; for 12h; Reagent/catalyst; Temperature; Solvent; Time; Molecular sieve;96%
With palladium/alumina In hexane at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;95.6%
With zirconium hydroxide; ethanol at 150℃; Flow reactor;84%

C13H21BO2

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water Inert atmosphere;95%
98-01-1

furfural

A

98-00-0

(2-furyl)methyl alcohol

B

4464-77-1, 69314-24-5, 69314-25-6, 116204-42-3

1,2-di-furan-2-yl-ethane-1,2-diol

Conditions
ConditionsYield
With potassium hydroxide at 20℃; under 760.051 Torr; Reagent/catalyst; Electrochemical reaction; Green chemistry;A n/a
B 94%
With sodium hydroxide; aluminium In methanol; water for 0.166667h; pinacol coupling; microwave irradiation;A 10%
B 70%
With acetic acid; zinc In water at 20℃; for 0.333333h; Green chemistry;A 39%
B 51%
With naphthalene; lithium; manganese(ll) chloride In tetrahydrofuran at 50 - 54℃; for 1h; sonication;A 12%
B 37%
With manganese; 2,4,6-collidine hydrochloride In tetrahydrofuran; water at 27℃; for 24h; Inert atmosphere; Schlenk technique; Overall yield = 95 %; Overall yield = 92 mg; chemoselective reaction;
Conditions
ConditionsYield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;A 59%
B 94%
C 1%
D 5%

2-(furan-2-ylmethoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With silica gel In ethyl acetate; Petroleum ether94%
With water; silica gel In methanol at 60℃; Inert atmosphere;88%
In methanol at 20℃; for 6h; Inert atmosphere; Glovebox;74%
67-47-0

5-hydroxymethyl-2-furfuraldehyde

A

534-22-5

2-methylfuran

B

98-00-0

(2-furyl)methyl alcohol

C

625-86-5

2,5-dimethylfuran

Conditions
ConditionsYield
With hydrogen In 1,4-dioxane at 180℃; under 11251.1 Torr; for 2h; Catalytic behavior;A n/a
B n/a
C 93.4%
2846-62-0

(furan-2-ylmethoxy)trimethylsilane

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With 1,4-diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles In methanol at 20℃; for 0.0833333h;93%
With water; boric acid at 20℃; for 1h;87%
With aminosulfonic acid; water at 20℃; for 2h;85%
98-01-1

furfural

108-91-8

cyclohexylamine

A

98-00-0

(2-furyl)methyl alcohol

B

4439-54-7

N-cyclohexan-1-(furan-2-yl)methanamine

C

69819-61-0

N-(furan-2-ylmethylene)cyclohexanamine

D

N-((tetrahydrofuran-2-yl)methyl)cyclohexanamine

Conditions
ConditionsYield
With hydrogen; Pd on polytris(hydroxymethyl)melamine In ethanol at 45℃; under 757.6 Torr; for 1h; Rate constant; Kinetics; activation energy, other catalysts: Pd/C, palladium on aminated and chloromethylated styrene-divinylbenzene copolymer anion exchange resin AV-17-8 matrix, other solvents: 1-propanol, 2-propanol, 1-butanol, 2-methyl-2-propanol, toluene, hexane;A n/a
B n/a
C n/a
D 92%
1899-24-7

5-bromo-2-furancarboxaldehyde

A

98-00-0

(2-furyl)methyl alcohol

B

27230-58-6

(5-bromo-2-furan-2-yl)methanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether at 0℃; for 2h;A 9%
B 91%
67-47-0

5-hydroxymethyl-2-furfuraldehyde

A

98-00-0

(2-furyl)methyl alcohol

B

823-82-5

2,5-diformylfurane

Conditions
ConditionsYield
With carbon dioxide; palladium/alumina In tetrahydrofuran at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;A 90.9%
B 5.5%
With Pd/γ-Al2O3 In 1,4-dioxane at 160℃; for 16h; Inert atmosphere; Autoclave;
98-01-1

furfural

A

97-99-4

Tetrahydrofurfuryl alcohol

B

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With hydrogen at 90℃; under 15001.5 Torr; Reagent/catalyst;A 90.5%
B 8.4%
With hydrogen In butan-1-ol at 40℃; under 30003 Torr; for 7h; Catalytic behavior; Reagent/catalyst;A 12%
B 85%
With hydrogen In tetrahydrofuran at 175℃; under 7500.75 Torr; for 8h; Catalytic behavior; Pressure; Temperature; Time; chemoselective reaction;A 10%
B 79.5%
58-86-6

D-xylose

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With dodecatungstosilic acid; formic acid In tert-butyl alcohol for 3h; Kinetics; Activation energy; Reagent/catalyst; chemoselective reaction;90.1%
Multi-step reaction with 2 steps
1.1: formic acid / tetrahydrofuran; dimethyl sulfoxide / 150 °C
2.1: Cp*Ir(TsDPEN); triethylamine / tetrahydrofuran; dimethyl sulfoxide / 0.08 h / 40 °C
2.2: 40 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium chloride; aluminum (III) chloride / iso-butanol / 140 °C / Autoclave
2: isopropyl alcohol; iron oxide / 5 h / 160 °C / Autoclave
View Scheme
98-01-1

furfural

67-63-0

isopropyl alcohol

A

98-00-0

(2-furyl)methyl alcohol

B

623-15-4

4-(furan-2-yl)but-3-en-2-one

C

113984-01-3

isopropopyl (2-methylfuran) ether

Conditions
ConditionsYield
With iron oxide at 160℃; for 5h; Reagent/catalyst; Temperature; Autoclave;A 90.1%
B n/a
C n/a
at 219.84℃; under 760.051 Torr; Temperature; Flow reactor; Inert atmosphere;
With 2 wt% MgO loaded on amorphous silica at 159.84℃; under 3750.38 Torr; for 12h; Reagent/catalyst; Inert atmosphere;A 9.2 %Chromat.
B 9.2 %Chromat.
C 14.2 %Chromat.
88-14-2

2-furanoic acid

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With strain of the zygomycete fungus S. racemosum MUT 770 In dimethyl sulfoxide for 72h; Enzymatic reaction;90%
Stage #1: 2-furanoic acid With trimethylphenylsilane; C69H55ClP3Ru In tetrahydrofuran at 60℃; for 16h; Glovebox;
Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 1h; Glovebox; chemoselective reaction;
65%
With sodium tetrahydroborate; N,N-dimethylchloromethyleniminium chloride 1.) acetonitrile, THF, 0 deg C, 1 h; 2.) acetonitrile, THF, N,N-dimethylformamide, -78 deg C to -20 deg C, 2 h; Yield given. Multistep reaction;
623-17-6

furfurylacetate

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With lipase B from Candida antarctica immobilized on Immobead 150 In aq. phosphate buffer at 40℃; for 0.333333h; pH=7.4;89%
With methanol; potassium permanganate; trimethylsulphonium iodide at 25℃; under 760.051 Torr; chemoselective reaction;80%
With methanol; potassium permanganate at 25℃; chemoselective reaction;78%
With [t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h; Deacetylation;82 % Chromat.
[t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h;82 % Chromat.
613-75-2

(furan-2-yl)methylene diacetate

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In methanol at 20℃; for 4h; chemoselective reaction;86%
498-60-2

furan-3-carboxaldehyde

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With C22H21ClN3RuS2(1+)*F6P(1-); isopropyl alcohol; potassium hydroxide In acetonitrile at 80℃; for 3h; Catalytic behavior; Concentration; Reagent/catalyst;85%

C11H12O2Si

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water Schlenk technique; Inert atmosphere;85%
With sodium hydroxide In water
98-01-1

furfural

A

534-22-5

2-methylfuran

B

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With hydrogen at 160℃; under 760.051 Torr; for 24h; Reagent/catalyst; Temperature;A n/a
B 84.7%
With hydrogen; CuO on Al2O3 at 250℃; Product distribution; gas phase, flow reactor, oth. temperature, var. ratio of reactants;A 69.7%
B 4.2%
With hydrogen In isopropyl alcohol at 200℃; under 22502.3 Torr; Autoclave;A 66%
B 6%
17357-38-9

S-phenyl furan-2-carbothioate

98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With zinc(II) tetrahydroborate In tetrahydrofuran; diethyl ether for 96h; Ambient temperature;84%
98-00-0

(2-furyl)methyl alcohol

97-99-4

Tetrahydrofurfuryl alcohol

Conditions
ConditionsYield
With 3% Pd/C; hydrogen In isopropyl alcohol at 219.84℃; under 25858.1 Torr; for 5h; Inert atmosphere;100%
With hydrogen In isopropyl alcohol at 25℃; under 7500.75 Torr; for 3h; Green chemistry;100%
With palladium on activated charcoal; ammonia; hydrogen In tetrahydrofuran at 160℃; for 4h; Reagent/catalyst; Autoclave;100%
98-00-0

(2-furyl)methyl alcohol

18162-48-6

tert-butyldimethylsilyl chloride

121389-55-7

tert-butyl(furan-2-ylmethoxy)dimethylsilane

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at -78 - 20℃;100%
With 1H-imidazole In N,N-dimethyl-formamide99%
With 1H-imidazole In N,N-dimethyl-formamide at 23℃; for 0.5h;97%
98-00-0

(2-furyl)methyl alcohol

106-96-7

propargyl bromide

32904-79-3

2-((prop-2-yn-1-yloxy)methyl)furan

Conditions
ConditionsYield
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 1.5h;
Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; Reagent/catalyst;
100%
With para-chlorotoluene; lithium In tetrahydrofuran at -35 - 20℃; for 10h; Heating / reflux;93%
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h;
Stage #2: propargyl bromide In N,N-dimethyl-formamide; toluene at 23℃; for 4h;
86%
98-00-0

(2-furyl)methyl alcohol

98-01-1

furfural

Conditions
ConditionsYield
With bis(2,2'-bipyridyl) copper(II) permanganate In acetone for 0.1h; Ambient temperature;100%
With 4 A molecular sieve; tetrabutylammonium perchlorate; Ru-Cu-Al-hydrotalcite In toluene at 60℃; for 3h;100%
With potassium carbonate In toluene at 70℃; for 2.5h; Reagent/catalyst;100%
98-00-0

(2-furyl)methyl alcohol

22536-63-6

2-chloro-4-methoxypyrimidine

2-(Furan-2-ylmethoxy)-4-methoxy-pyrimidine

Conditions
ConditionsYield
With sodium alkoxide100%
98-00-0

(2-furyl)methyl alcohol

potassium 4-(methoxy)phenyltrifluoroborate

2-(4-methoxyphenoxymethyl) furan

Conditions
ConditionsYield
Stage #1: potassium 4-(methoxy)phenyltrifluoroborate With dmap; copper diacetate; 4 A molecular sieve In dichloromethane at 20℃; for 0.0833333h;
Stage #2: (2-furyl)methyl alcohol With oxygen In dichloromethane at 20℃; for 24h;
100%
98-00-0

(2-furyl)methyl alcohol

819813-95-1

2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

819813-96-2

N-furfuryl-2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In toluene at 20℃; for 1h;100%
504-29-0

2-aminopyridine

98-00-0

(2-furyl)methyl alcohol

46230-01-7

furan-2-ylmethyl-pyridin-2-yl-amine

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]; potassium tert-butylate In tetrahydrofuran; toluene at 110℃; for 24h; Inert atmosphere; Molecular sieve;81%
With C46H45ClN4PRu(1+)*F6P(1-); potassium 2-methylbutan-2-olate In toluene at 150℃; for 18h;77%
98-00-0

(2-furyl)methyl alcohol

62-53-3

aniline

4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-methylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With titanium triflimide complex; pyridine ligand In toluene at 100℃; for 2h; Microwave irradiation;98%
With C36H35IrN2P(1+)*C32H12BF24(1-); potassium tert-butylate In diethylene glycol dimethyl ether at 50℃; for 24h; Inert atmosphere;94%
98-00-0

(2-furyl)methyl alcohol

546-68-9

titanium(IV) isopropylate

1346523-07-6

C16H24O6Ti

Conditions
ConditionsYield
In cyclohexane Inert atmosphere; Reflux;100%
In cyclohexane for 0.5h; Schlenk technique; Inert atmosphere; Reflux;100%
98-00-0

(2-furyl)methyl alcohol

79-04-9

chloroacetyl chloride

51618-39-4

(furan-2-yl)methyl 2-chloroacetate

Conditions
ConditionsYield
With pyridine In diethyl ether at 0℃;100%
98-00-0

(2-furyl)methyl alcohol

95-68-1

2,4-Xylidine

C13H15NO

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-isopropylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With dichloro(1‐(2‐vinyloxyethyl)benzimidazole)‐(p‐cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Schlenk technique; Inert atmosphere;
With [dichloro‑[1,3‑bis(4‑phenylbenzyl)perhydrobenzimidazol‑2‑ylidene](η6-p‑cymene)ruthenium(II)]; potassium tert-butylate In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100 %Chromat.
With potassium tert-butylate; C46H56Cl2N2Ru In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;76 %Chromat.
98-00-0

(2-furyl)methyl alcohol

4-methyl-2-oxo-2H-chromen-7-yl carbonochloridate

furan-2-ylmethyl (4-methyl-2-oxo-2H-chromen-7-yl) carbonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;100%
98-00-0

(2-furyl)methyl alcohol

123-76-2

levulinic acid

furfuryl levulinate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 3h;100%
98-00-0

(2-furyl)methyl alcohol

67-56-1

methanol

Nafion-H

Nafion-H

624-45-3

levulinic acid methyl ester

Conditions
ConditionsYield
at 20 - 80℃; for 6h; Temperature; Reagent/catalyst;99.32%
98-00-0

(2-furyl)methyl alcohol

71-36-3

butan-1-ol

2052-15-5

butyl levulinate

Conditions
ConditionsYield
With 5-sulfosalicylic Acid at 118℃; under 760.051 Torr; for 10h; Catalytic behavior; Temperature;99.3%
With toluene-4-sulfonic acid at 80℃; for 4h; Reagent/catalyst; Temperature; Inert atmosphere;94.2%
With [BmimSO3H]3PW12O40; water at 110℃; for 12h;93%
98-00-0

(2-furyl)methyl alcohol

109-87-5

Dimethoxymethane

126825-52-3

2-((methoxymethoxy)methyl)furan

Conditions
ConditionsYield
With Mo(VI)/ZrO2 at 40℃; for 0.333333h; Reagent/catalyst; Reflux; Inert atmosphere; Green chemistry;99.2%
98-00-0

(2-furyl)methyl alcohol

75-15-0

carbon disulfide

89712-86-7

potassium O-furfuryl dithiocarbonate

Conditions
ConditionsYield
With potassium hydroxide In diethyl ether at 20℃; for 12h;99%
With potassium hydroxide In acetone67%
With potassium hydroxide
With potassium hydroxide In tetrahydrofuran at 20℃; under 760.051 Torr;
With potassium hydroxide
98-00-0

(2-furyl)methyl alcohol

108-24-7

acetic anhydride

623-17-6

furfurylacetate

Conditions
ConditionsYield
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.0833333h;99%
tetradecafluorohexane at 20℃; for 6h;99%
With [{CpHf(OH2)3}2(μ2-OH)2][OSO2C8F17]4*4H20*2THF at 20℃; for 0.0833333h; chemoselective reaction;98%
98-00-0

(2-furyl)methyl alcohol

88-14-2

2-furanoic acid

Conditions
ConditionsYield
With manganese(IV) oxide; oxygen; sodium hydrogencarbonate In water at 100℃; under 7500.75 Torr; for 24h;99%
With oxygen; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride; sodium t-butanolate In dichloromethane at 20℃; for 30h; Reagent/catalyst; Molecular sieve;95%
With sodium carbonate In water at 30℃; for 40h; Wavelength; Irradiation;93%
98-00-0

(2-furyl)methyl alcohol

922-67-8

propynoic acid methyl ester

methyl (E)-3-(furan-2-ylmethoxy)acrylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In dichloromethane99%
With tributylphosphine In dichloromethane for 0.0833333h; Ambient temperature;98%
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water at 240℃; Temperature; Reagent/catalyst; Solvent; Autoclave;99%
With sodium hydroxide In water at 240℃; for 0.02h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Autoclave;99%
With sodium hydroxide In water at 240℃; for 0.02h; Reagent/catalyst; Temperature; Solvent; Concentration;99%
98-00-0

(2-furyl)methyl alcohol

999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

2846-62-0

(furan-2-ylmethoxy)trimethylsilane

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide In dichloromethane at 20℃; for 0.166667h; chemoselective reaction;99%
With lithium perchlorate; silica gel In dichloromethane at 20℃; for 0.0833333h;96%
With Nafion SAC-13 at 20℃; for 0.0833333h;96%
98-00-0

(2-furyl)methyl alcohol

2325-27-1

N-phenyltriphenyliminophosphorane

4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
With cesium hydroxide; palladium diacetate In toluene at 150℃; for 48h; Aza-Wittig reaction;99%
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; bis(1,5-cyclooctadiene)diiridium(I) dichloride In toluene at 110℃; for 24h; indirect aza-Wittig reaction;71%
98-00-0

(2-furyl)methyl alcohol

60750-38-1

1,2,3,4-tetrahydro-1,6-dimethyl-2-oxo-4-phenylpyrimidine-5-carboxylic acid

95928-47-5

Furfuryl Ester of 1,6-Dimethyl-4-phenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic Acid

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 0.00833333h; Mitsunobu esterification;99%
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    Siwei Development Group Ltd. is a reputed professional enterprise in China dedicated to the Amino Acids production and sales of fine chemical products.Over the years we have been m

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Chemistry

The Molecular Structure of Furfuryl alcohol (CAS NO.98-00-0):


Empirical Formula: C5H6O2
Molecular Weight: 98.0999 
IUPAC Name: furan-2-ylmethanol    
Product Categories: Furans;alcohol Flavor
Appearance: clear yellow liquid
Nominal Mass: 98 Da
Average Mass: 98.0999 Da
Monoisotopic Mass: 98.036779 Da 
Index of Refraction: 1.492
Molar Refractivity: 25 cm3
Molar Volume: 86 cm3
Surface Tension: 38.8 dyne/cm
Density: 1.14 g/cm3
Flash Point: 65 °C
Enthalpy of Vaporization: 42.98 kJ/mol
Boiling Point: 170 °C at 760 mmHg
Vapour Pressure: 1.01 mmHg at 25°C
Melting point: -29 ºC
Refractive index: 1.485-1.487
Water solubility: MISCIBLE 
InChI
InChI=1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H2
Smiles
Synonyms: c1(ccco1)CO ; AI3-01171 ; BRN 0106291 ; CCRIS 2922 ; NCI-C56224 ; NSC 8843 ; UNII-D582054MUH ; EINECS 202-626-1 ; FEMA No. 2491 ; UN2874 ; HSDB 711  

Uses

 Furfuryl alcohol (CAS NO.98-00-0) has been used in rocketry as a fuel which ignites hypergolically (immediately and energetically in contact) with white fuming nitric acid or red fuming nitric acid oxidizer.The use of hypergolics avoids the need for an igniter. Furfuryl alcohol (CAS NO.98-00-0) is probably a BK channel agonist.and may be used as a food additive.

Production

 Furfuryl alcohol (CAS NO.98-00-0) is manufactured industrially by the catalytic reduction of FURFURAL which is obtained from corncobs and sugar cane bagasse. It finds use as a solvent, but is primarily used as an ingredient in the manufacture of various chemical products such as foundry resins, adhesives, and wetting agents.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 oral 360mg/kg (360mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse LCLo inhalation 597ppm/6H (597ppm)   "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
mouse LD50 oral 160mg/kg (160mg/kg)   Biochemical Journal. Vol. 34, Pg. 1196, 1940.
mouse LD50 unreported 338mg/kg (338mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rabbit LD50 intravenous 650mg/kg (650mg/kg)   Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 8, Pg. 294, 1949.
rabbit LD50 skin 400mg/kg (400mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rabbit LD50 unreported 632mg/kg (632mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rat LC50 inhalation 233ppm/4H (233ppm)   American Industrial Hygiene Association Journal. Vol. 19, Pg. 91, 1958.
 
rat LD50 intraperitoneal 650mg/kg (650mg/kg)   Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 64, 1974.
rat LD50 oral 177mg/kg (177mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat LD50 skin 3825mg/kg (3825mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat LD50 subcutaneous 85mg/kg (85mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rat LD50 unreported 460mg/kg (460mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.

Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 20/21/22 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 23-36/37/39 
S23: Do not breathe vapour
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR: UN 2874 6.1/PG 3
WGK Germany: 1
RTECS: LU9100000
F 8: Photosensitive
HazardClass: 6.1
PackingGroup: III

Specification

 Furfuryl alcohol (CAS NO.98-00-0) is also called as 2-Furancarbinol ; 2-Furanmethanol ; 2-Furfuryl alcohol ; 2-Furfurylalkohol [Czech] ; 2-Furylcarbinol ; 5-Hydroxymethylfuran ; 2-Hydroxymethylfuran ; Furfuranol ; Furfurylcarb ; Furylcarbinol (VAN) ; Methanol, (2-furyl)- ; alpha-Furylcarbinol . Furfuryl alcohol is an organic compound containing a furan substitited with a hydroxymethyl group. It is a clear amber liquid with a faint burning odor and a bitter taste. It is soluble in common organic solvents. Upon treatment with acids, heat and/or catalysts,   furfuryl alcohol can be made to polymerize into a resin, poly .