Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With magnesium(II) perchlorate; polymer-bound NADH (2a) In acetonitrile; benzene at 80℃; for 120h; Further byproducts given; | 100% |
With carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)-amino]ruthenium(II); hydrogen; sodium hydrogencarbonate In methanol at 25℃; under 7500.75 Torr; for 12h; Glovebox; Autoclave; chemoselective reaction; | 98% |
With hydrogen; Et4N | 91% |
Conditions | Yield |
---|---|
tetrabutoxytitanium at 170℃; for 4h; Product distribution / selectivity; | 99.8% |
Conditions | Yield |
---|---|
With tin containing MWW type β-zeolite In decane at 119.84℃; for 24h; Reagent/catalyst; | 99% |
With Y-zeolite H-USY-6 In water at 115℃; for 24h; Inert atmosphere; | 96% |
With Sn(salen) functionalized [OMIm]Br at 160℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction; | 95.5% |
Conditions | Yield |
---|---|
With tin containing MWW type β-zeolite In decane at 119.84℃; for 24h; Reagent/catalyst; | 99% |
With Y-zeolite H-USY-6 In water at 115℃; for 48h; Inert atmosphere; | 98% |
With Sn(salen) functionalized [OMIm]Br at 160℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction; | 91.7% |
Conditions | Yield |
---|---|
98.8% |
Conditions | Yield |
---|---|
With iron(III) sulfate; sulfuric acid for 3h; Heating; | 97% |
With ethenetetracarbonitrile for 48h; Ambient temperature; | 88% |
at 25 - 72℃; Product distribution / selectivity; | 87% |
Conditions | Yield |
---|---|
With phosphotungstic acid at 130℃; for 4h; Reagent/catalyst; Autoclave; Inert atmosphere; Green chemistry; | 96% |
With Na/MgO at 160℃; under 30402 Torr; for 5h; Reagent/catalyst; Inert atmosphere; | 80% |
With magnesium oxide at 300℃; under 150015 Torr; for 1.5h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; | 23.9 mol |
With oxygen at 160℃; under 3750.38 Torr; Reagent/catalyst; Temperature; Autoclave; | |
With air; AuPd/carbon nanotubes + Sn-MCM-41-XS at 140℃; under 22502.3 Torr; for 4.5h; Catalytic behavior; Reagent/catalyst; Autoclave; Green chemistry; | 90 %Chromat. |
Conditions | Yield |
---|---|
iodine for 15h; Heating; | 90% |
methanol
dihydroxyacetone
A
methyl lactate
B
2-hydroxy-3-methoxypropionaldehyde
Conditions | Yield |
---|---|
With calcined Sn-modified beta zeolite at 70℃; for 4h; | A 86% B n/a |
Conditions | Yield |
---|---|
With hydrogenchloride; water at -10 - -5℃; for 4h; Reflux; | 85.58% |
1. | ipr-rat LDLo:>2 g/kg | JPPMAB Journal of Pharmacy and Pharmacology. 11 (1959),150. |