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| CAS No.: | 56-82-6 |
|---|---|
| Name: | DL-GLYCERALDEHYDE |
| Article Data: | 159 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H6 O3 |
| Molecular Weight: | 90.0788 |
| Synonyms: | Glyceraldehyde,DL- (8CI); Propanal, 2,3-dihydroxy-, (?à)-; (?à)-Glyceraldehyde; 2,3-Dihydroxypropanal; 2,3-Dihydroxypropionaldehyde;DL-Glyceraldehyde; DL-Glyceric aldehyde; Glyceraldehyde; Glyceric aldehyde;Glycerinaldehyde; Glycerose; NSC 67934; dl-Glyceraldehyde; a,b-Dihydroxypropionaldehyde |
| Density: | 1.593 g/cm3 (-5℃) |
| Melting Point: | 144-145oC(lit.) |
| Boiling Point: | 107.25°C (rough estimate) |
| Solubility: | 29.13g/L(18 oC) |
| Safety: | Mildly toxic by intraperitoneal route. Mutation data reported. |
| PSA: | 57.53000 |
| LogP: | -1.46150 |
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| Conditions | Yield |
|---|---|
| With nano-MnO2; graphite at 75℃; for 1.5h; Electrochemical reaction; Ultrasonic; | 91.6% |
| With oxygen In water at 45 - 50℃; for 5h; Reagent/catalyst; | 91% |
| With tert.-butylhydroperoxide; C56H62Cl2Mn2N6O10P2 In water; acetonitrile at 80℃; for 4h; Catalytic behavior; Green chemistry; | 44% |
| Conditions | Yield |
|---|---|
| With oxygen In water at 60℃; Catalytic behavior; Reagent/catalyst; Autoclave; chemoselective reaction; | A 84.2% B 9.5% C 6.3% |
| With oxygen In water at 60℃; under 760.051 Torr; for 4h; Catalytic behavior; | |
| With Pt-MCM-41 catalyst; oxygen In water at 69.84℃; under 760.051 Torr; pH=Ca. 7; Kinetics; Catalytic behavior; Reagent/catalyst; Temperature; |
| Conditions | Yield |
|---|---|
| With aluminum (III) chloride; tin(ll) chloride In water at 189.84℃; under 22502.3 Torr; for 2h; Catalytic behavior; Inert atmosphere; Autoclave; | A 81% B 5.2% |
- 130998-84-4
rac-Glycerinaldehyd-2-phosphat Natriumsalz
B
- 56-82-6
Glyceraldehyde
| Conditions | Yield |
|---|---|
| In aq. phosphate buffer at 60℃; for 23h; pH=7; | A 74% B 12% |
| Conditions | Yield |
|---|---|
| With silver dodecamolybdophosphate; oxygen In water at 60℃; under 3750.38 Torr; for 5h; Catalytic behavior; Reagent/catalyst; Autoclave; | A 72% B n/a C n/a |
| With phosphomolybdic acid; dihydrogen peroxide at 60℃; for 0.133333h; Catalytic behavior; | A 42% B n/a C n/a |
| With MoO40W12(3-)*Cr(3+); oxygen In water at 60℃; under 7500.75 Torr; for 20h; Autoclave; | A 12.9% B 8.6% C 5.9% |
- 67-56-1
methanol
A
- 530-26-7
D-Mannose
B
- 27871-49-4
(S)-Methyl lactate
C
- 1663-35-0
2-methoxyethyl vinyl ether
D
- 5837-73-0
methyl 2-hydroxybut-3-enoate
E
- 1186-47-6
1,1-dihydroxyacetone
F
- 56-82-6
Glyceraldehyde
G
- 621-63-6
glycoaldehyde diethyl acetal
| Conditions | Yield |
|---|---|
| With potassium carbonate at 160℃; for 16h; Reagent/catalyst; Flow reactor; | A n/a B 72% C n/a D n/a E n/a F n/a G n/a |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; sodium hydroxide In water; water-d2 for 59h; pH=5; | A 72% B 10% |
| With hydrogenchloride; sodium hydroxide In water; water-d2 for 30h; pH=3; | A 17% B 29% |
| Conditions | Yield |
|---|---|
| With perchloric acid In ethanol at 20℃; pH=1; Concentration; Reagent/catalyst; Electrochemical reaction; | A 9% B 70.6% |
| With Pseudomonas putida HK-5 pyrroloquinoline quinone-dependent alcohol dehydrogenase; 4,4'-azobis(1-methylpyridinium) bis(methyl sulfate); NADH In aq. buffer for 6h; pH=7.1; Catalytic behavior; Time; Electrolysis; Enzymatic reaction; | A 53% B 15% |
| With silica-supported platinum; oxygen In water at 89.84℃; for 24h; |
| Conditions | Yield |
|---|---|
| With potassium hydroxide for 4h; Reagent/catalyst; Electrochemical reaction; | A 70% B 13% C 17% |
| With dihydrogen peroxide In water at 60℃; for 4h; |
| Conditions | Yield |
|---|---|
| With triethylamine In N,N-dimethyl-formamide at 120℃; under 15751.6 Torr; for 1h; Temperature; Pressure; Reagent/catalyst; Solvent; | A 63.52% B 23.12% |
| With triethylamine In N,N-dimethyl-formamide at 100℃; under 3750.38 Torr; for 1h; Temperature; Pressure; Reagent/catalyst; Solvent; | A 25.17% B 38.23% |
| With 5-methoxy-1,3,4-triphenyl-4,5-dihydro-1H-1,2-4-triazoline In various solvent(s) at 80℃; |
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Chemistry
Molecular Structure of Dl-glyceraldehyde (CAS NO.56-82-6):
IUPAC: 2,3-dihydroxypropanal
Molecular Formula:C3H6O3
Molecular Weight:90.08
EINECS:200-290-0
Density:1.272 g/cm3
Melting Point:144-145oC(lit.)
Flash Point:106oC
Boiling Point:228oC at 760 mmHg
Storage temp.:2-8oC
Product Categories:Carbohydrate;Metabolic Pathways;Metabolites and Cofactors on the Metabolic Pathways Chart
SMILES:O=C[C@@H](O)CO
InChI:InChI=1/C3H6O3/c4-1-3(6)2-5/h1,3,5-6H,2H2/t3-/m1/s1
InChIKey:MNQZXJOMYWMBOU-GSVOUGTGBZ
Index of Refraction:1.454
Molar Volume:70.7 cm3
Surface Tension:53.3 dyne/cm
Molar Refractivity:19.16 cm3
Enthalpy of Vaporization:54.01 kJ/mol
Vapour Pressure:0.0146 mmHg at 25oC
Toxicity Data With Reference
| 1. | mmo-sat 100 µg/plate ABCHA6 47,2461,83 | |||
| 2. | ipr-rat LD50:2 g/kg | JPPMAB Journal of Pharmacy and Pharmacology. 17 (1965),814. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Mildly toxic by intraperitoneal route. Mutation data reported.
Safty informations about Dl-glyceraldehyde (CAS NO.56-82-6):
WGK Germany:3
RTECS:MA6475000
F:10-23
Specification
Dl-glyceraldehyde with cas registry number of 56-82-6 is also known as Glyceric aldehyde ; Glyceraldehyde ; Dl-glyceraldehyde ; (+-)-Glyceraldehyd ; 3-Dihydroxy-(+/-)-propana ; Dl-glyceraldehyd ; Dl-glycericaldehyde ; Dl-glyceraldehyde crystalline . It is a compound with the appearance of white crystalline powder. It is soluble in water. Dl-glyceraldehyde is used as an organic synthesis intermediate in synthesis of many useful compounds. It is also used in biochemical research.