Basic Information | Post buying leads | Suppliers | Cas Database |
Conditions | Yield |
---|---|
With magnesium In diethyl ether at 25℃; under 5171.62 Torr; Inert atmosphere; Flow reactor; | 94% |
With magnesium In diethyl ether | |
With magnesium In solid matrix at -258.2℃; |
Conditions | Yield |
---|---|
Katalytischer Einfluss; |
Conditions | Yield |
---|---|
With diethyl ether |
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at -78 - 20℃; Nitrogen atmosphere; | 100% |
With diethyl ether |
methyl magnesium iodide
9,10-diformylanthracene
9,10-bis(1-hydroxymethyl)anthracene
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at 40℃; for 8h; | 100% |
In tetrahydrofuran; diethyl ether at 20℃; for 18h; | 100% |
methyl magnesium iodide
2-bromo-4,5-dimethoxybenzaldehyde
6-bromo-3,4-dimethoxy-α-methylbenzyl alcohol
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 0.5h; | 100% |
In tetrahydrofuran; diethyl ether for 1h; Heating; | 100% |
In diethyl ether at 0 - 20℃; for 3h; Inert atmosphere; | 90% |
In diethyl ether at 20℃; for 0.5h; |
methyl magnesium iodide
7β-acetyl-4aβ-methyl-1aα-decahydrocyclopropanaphthalene
(+)-7β-(1-hydroxy-1-methylethyl)-4aB-methyl-1aα-decahydrocyclopropanaphthalene
Conditions | Yield |
---|---|
In diethyl ether for 2h; Ambient temperature; | 100% |
methyl magnesium iodide
methyl 4-(4-methylphenyl)butanoate
2-(methyl-5-(4-methylphenyl))-2-pentanol
Conditions | Yield |
---|---|
In diethyl ether for 24h; Ambient temperature; | 100% |
methyl magnesium iodide
2-iodo-4,5-dimethoxybenzaldehyde
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether for 1h; Heating; | 100% |
The Molecular Structure of Magnesium, iodomethyl- (CAS NO.917-64-6):
Molecular Formula: CH3IMg
Molecular Weight: 166.24
Density: 1.26 g/mL at 20 °C
Product Categories: Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents
ACD/LogP: 1.09
ACD/LogD (pH 5.5): 1.09
ACD/LogD (pH 7.4): 1.09
ACD/BCF (pH 5.5): 3.97
ACD/BCF (pH 7.4): 3.97
ACD/KOC (pH 5.5): 93.32
ACD/KOC (pH 7.4): 93.32
Enthalpy of Vaporization: 8.17 kJ/mol
Vapour Pressure: 205000 mmHg at 25°C
Toxic. Explosive reaction with thiophosphoryl chloride or vanadium trichloride. A Grignard reagent. When heated to decomposition it emits toxic fumes of I−. See also IODIDES and MAGNESIUM COMPOUNDS.
Hazard Codes:F+,C
Risk Statements: 12-14/15-22-34-66-67
R12:Extremely flammable
R14/15: Reacts violently with water, liberating extremely flammable gases
R22: Harmful if swallowed
R34: Causes burns
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapours may cause drowsiness and dizziness
Safety Statements: 16-26-36/37/39-43-45-7/8
S16: Keep away from sources of ignition
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice|
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
7/8: Keep container tightly closed and dry
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10
F1: Sensitive to air and humidity
F3: Hygroscopic
F10: Keep under argon
HazardClass: 4.2
PackingGroup: I
Magnesium, iodomethyl- (CAS NO.917-64-6) is also called as Iodomethylmagnesium ; Magnesium, iodomethyl- .