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Cas Database

Name	N-(Hydroxymethyl)acetamide	EINECS	210-897-2
CAS No.	625-51-4	Density	1.14
PSA	49.33000	LogP	-0.53680
Solubility	soluble	Melting Point	48-52 °C
Formula	C3H7 N O2	Boiling Point	321.3 °C at 760 mmHg
Molecular Weight	89.0941	Flash Point	148.1 °C
Transport Information	N/A	Appearance	white solid
Safety	22-24/25	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Acetamidomethanol;Formicin; Monomethylolacetamide; N-(Hydroxymethyl)acetamide;N-Methylolacetamide; N-Monomethylolacetamide	Article Data	26

N-(Hydroxymethyl)acetamide Synthetic route

: 60-35-5
acetamide

: 50-00-0
formaldehyd

: 625-51-4
N-(hydroxymethyl)acetamide

Conditions

Conditions	Yield
With potassium carbonate
Versetzen mit 40prozentiger KOH;
With potassium carbonate

: 60-35-5
acetamide

: 50-00-0
formaldehyd

A: 3852-14-0
N,N-methylenediacetamide

B: 625-51-4
N-(hydroxymethyl)acetamide

Conditions

Conditions	Yield
In 1,4-dioxane; water at 40 - 60℃; Thermodynamic data; Kinetics; Mechanism; activation energy, pH 1.2-3.5;

: 556-50-3
glycylglycine

A: 625-51-4
N-(hydroxymethyl)acetamide

B: {2-[(Acetylamino-methyl)-amino]-acetylamino}-acetic acid

Conditions

Conditions	Yield
In water Mechanism; Quantum yield; Irradiation; neutral solution;

: 556-50-3
glycylglycine

A: 60-35-5
acetamide

B: 3852-14-0
N,N-methylenediacetamide

C: 625-51-4
N-(hydroxymethyl)acetamide

D: 543-24-8
N-acetylglycine

Conditions

Conditions	Yield
In water Product distribution; Quantum yield; Mechanism; Irradiation; pH 6; var. dipeptides, other pH and times;

: 32516-05-5
3,7-diacetyl-1,3,5,7-tetraaza-bicyclo[3.3.1]nonane

A: 50-00-0
formaldehyd

B: 625-51-4
N-(hydroxymethyl)acetamide

Conditions

Conditions	Yield
With hydrogenchloride In water at 25℃; for 0.333333h;	A 1.7 % Turnov. B n/a

: 60-35-5
acetamide

polyoxymethylene: polyoxymethylene

: 625-51-4
N-(hydroxymethyl)acetamide

Conditions

Conditions	Yield
at 120 - 150℃;

: 224633-83-4
6-methyl-2-p-tolyl-imidazo[1,2-a]pyridin-4-ium bromide

: 625-51-4
N-(hydroxymethyl)acetamide

: 103844-36-6
C18H19N3O

Conditions

Conditions	Yield
Stage #1: 6-methyl-2-p-tolyl-imidazo[1,2-a]pyridin-4-ium bromide; N-(hydroxymethyl)acetamide With sulfuric acid In acetic acid at 20℃; for 3.5h; Heating / reflux; Stage #2: With ammonia In water; acetic acid	97%

: 625-51-4
N-(hydroxymethyl)acetamide

: 177412-46-3
5,17-dibromo-25,27-bis(2-ethoxyethoxy)calix[4]arene

: 5,17-bis<(acetamido)methyl>-26,28-dihydroxy-25,27-bis(2-ethoxyethoxy)calix<4>arene

Conditions

Conditions	Yield
With trifluoroacetic acid In chloroform Ambient temperature;	95%

: 21407-29-4
2-mercapto-4,5-dimethoxybenzylamine hydrochloride

: 625-51-4
N-(hydroxymethyl)acetamide

: S-acetamidomethyl 4,5-dimethoxy-2-mercaptobenzylamine hydrochloride

Conditions

Conditions	Yield
With hydrogenchloride	94%

: 99-24-1
methyl galloate

: 625-51-4
N-(hydroxymethyl)acetamide

: C11H13NO6

Conditions

Conditions	Yield
With sulfuric acid In ethanol at 35℃; for 96h; Friedel-Crafts Alkylation;	91.36%

N-(Hydroxymethyl)acetamide Chemical Properties

The molecular formula of N-(Hydroxymethyl)acetamide(625-51-4) is C₃H₇NO₂ and its formula weight is 89.09.
The density of N-(Hydroxymethyl)acetamide(625-51-4) is 1.093 g/cm³ and it has a melting point of 48-52 °C. The boiling point is 321.3 °C at 760 mmHg. The refractive index is about 1.431. Its flash point is 148.1 °C.
The chemical synonyms of N-(Hydroxymethyl)acetamide(625-51-4) are ACETAMIDOMETHANOL;HYDROXYMETHYLACETAMIDE(N-);N-(HYDROXYMETHYL)ACETAMIDE;N-ACETYLMETHANOLAMINE;n-(hydroxymethyl)-acetamid;N-(Hydroxymethyl)acetamide,98+%;Hydroxymethylacetamide
The molecular structure of N-(Hydroxymethyl)acetamide(625-51-4):

N-(Hydroxymethyl)acetamide Safety Profile

Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3

RTECS AC3610000

F 10

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N-(Hydroxymethyl)acetamide

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