- Nitrogen
- Nitrogen chloride
- Nitrogen dioxide
- Nitrogen Fluoride Oxide
- Nitrogen monoxide, mixed with nitrogen tetroxide
- Nitrogen oxide (N2O5)
- NITROGEN TETROXIDE
- NITROGEN TRIFLUORIDE
- Nitrogen triiodide
- 10025-87-3Phosphorus oxychloride
- 10025-90-8Praseodymium chloride(PrCl3), heptahydrate (8CI,9CI)
- 10025-91-9Stibine, trichloro-
- 10025-94-2Yttrium chloride(YCl3), hexahydrate (8CI,9CI)
- 10025-97-5Iridium chloride(IrCl4)
- 10025-98-6Palladate(2-),tetrachloro-, potassium (1:2), (SP-4-1)-
- 10025-99-7Platinate(2-),tetrachloro-, potassium (1:2), (SP-4-1)-
- 10026-00-3Platinate(2-),tetrachloro-, sodium (1:2), (SP-4-1)-
- 10026-04-7Silane, tetrachloro-
- 10026-06-9Stannane, tetrachloro-,hydrate (1:5)
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Cas Database |
| Name |
Nitrogen chloride |
EINECS | 233-045-1 |
| CAS No. | 10025-85-1 | Density | 1.72 g/cm3 |
| PSA | 3.24000 | LogP | 1.74980 |
| Solubility | Immiscible | Melting Point |
-40 °C (233 K) |
| Formula | Cl3N | Boiling Point | 70 °C at 760 mmHg |
| Molecular Weight | 120.366 | Flash Point | °C |
| Transport Information | N/A | Appearance | Yellow oily liquid |
| Safety | Moderately toxic by inhalation. An irritant to the eyes, skin, mucous membranes, and a systemic central nervous system irritant. An explosive sensitive to impact, light, and ultrasound. The solid explodes on melting. The liquid explodes above 60°C. Concentrated solutions are also explosive. Explosive decomposition is initiated by contact with: concentrated ammonia, arsenic, dinitrogen tetraoxide, hydrogen sulfide, hydrogen trisulfide, nitrogen oxide, organic matter, ozone, phosphine, phosphorus, potassium cyanide, potassium hydroxide solutions, selenium, hydrogen chloride, hydrogen fluoride, hydrogen bromide, hydrogen iodide. Mixtures with chlorine + hydrogen are potentially explosive. Upon decomposition it emits toxic fumes of Cl− and NOx. See also CHLORIDES. | Risk Codes | R36/37/38; R34; R10 |
| Molecular Structure |
|
Hazard Symbols | Explodes when heated to approximately 200F (93C) or when exposed to direct sunlight. Toxic by ingestion and inhalation, strong irritant. |
| Synonyms |
Agene;Chlorine nitride; Nitrogen trichloride; Trichloramine; Trichlorine nitride;Trichloroamine |
Article Data | 156 |
Nitrogen chloride Synthetic route
| Conditions | Yield |
|---|---|
| With hydrogenchloride In dichloromethane; water at 4℃; for 0.75h; |
| Conditions | Yield |
|---|---|
| In water Electrolysis; |
- 2696-92-6
nitrosylchloride
A
- 81390-26-3, 35576-91-1, 81407-93-4
nitrosoamine
B
- 10025-85-1
nitrogen trichloride
| Conditions | Yield |
|---|---|
| With ammonia In neat (no solvent) reaction of NOCl with melted NH3;; |
- 10026-13-8, 874483-75-7
phosphorus pentachloride
- 2696-92-6
nitrosylchloride
A
- 10025-85-1
nitrogen trichloride
B
- 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate
| Conditions | Yield |
|---|---|
| In not given react. with NOCl;; | |
| In not given educts are passed through a porcelain tube heated at 1000 to 1100.degreeC;; very poor yield;; | |
| In not given heating;; | |
| In not given educts are passed through a porcelain tube heated at 1000 to 1100.degreeC;; very poor yield;; |
- 7727-37-9
nitrogen
- 10102-43-9
nitrogen(II) oxide
- 10294-34-5
boron trichloride
A
- 10025-85-1
nitrogen trichloride
B
- 12505-77-0
boron monoxide
| Conditions | Yield |
|---|---|
| with "active N" in presence of traces of O2; | |
| with "active N" in presence of traces of O2; |
- 302-01-2
hydrazine
- 10025-85-1
nitrogen trichloride
| Conditions | Yield |
|---|---|
| With chlorine with chlorine excess, in presence of CCl4; | |
| With Cl2 with chlorine excess, in presence of CCl4; |
| Conditions | Yield |
|---|---|
| with dried gases at ambient temp., under 25 Torr; at higher pressure no NCl3 formed; | |
| In tetrachloromethane at -90 and -180°C;; | |
| In pentane at -90 and -180°C;; |
| Conditions | Yield |
|---|---|
| In water; sodium chloride Electrolysis; the anode is graphite, cathode is platimun wire; |
- 10025-85-1
nitrogen trichloride
| Conditions | Yield |
|---|---|
| In not given Electrolysis; a cold satd. soln. is used;; | |
| In water Electrolysis; NCl3 is formed at a platinum anode and explodes at touching of both poles;; | |
| In water Electrolysis; electrolysis of concd. NH4Cl soln. at 35 - 40°C; don't stirring soln.;; |
| Conditions | Yield |
|---|---|
| In water reaction of acidified NH4Cl soln. with calcd. amount of Ca(ClO)2;; chloride free NCl3;; | |
| In water reaction of acidified NH4Cl soln. with calcd. amount of Ca(ClO)2;; chloride free NCl3;; |
Nitrogen chloride Chemical Properties
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Product Name: Trichlorine nitride
Molecular Weight: 120.3657 g/mol
Molecular Formula: Cl3N
Canonical SMILES: N(Cl)(Cl)Cl
InChI: InChI=1S/Cl3N/c1-4(2)3
EINECS: 233-045-1
Index of Refraction: 1.492
Molar Refractivity: 20.31 cm3
Molar Volume: 69.9 cm3
Surface Tension: 37.5 dyne/cm
Density: 1.72 g/cm3
Enthalpy of Vaporization: 31.16 kJ/mol
Boiling Point: 70 °C at 760 mmHg
Vapour Pressure of Nitrogen chloride (CAS NO.10025-85-1): 131 mmHg at 25 °C
Nitrogen chloride Uses
Nitrogen Chloride (CAS NO.10025-85-1) was trademarked as Agene and used to artificially bleach and age flour. It has the same effect as that of tear gas, but has never been used as such.
Nitrogen chloride Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rat | LC50 | inhalation | 112ppm/1H (112ppm) | sense organs and special senses: lacrimation: eye behavioral: convulsions or effect on seizure threshold gastrointestinal: changes in structure or function of salivary glands | American Industrial Hygiene Association Journal. Vol. 44, Pg. 145, 1983. |
Nitrogen chloride Safety Profile
Moderately toxic by inhalation. An irritant to the eyes, skin, mucous membranes, and a systemic central nervous system irritant. An explosive sensitive to impact, light, and ultrasound. The solid explodes on melting. The liquid explodes above 60°C. Concentrated solutions are also explosive. Explosive decomposition is initiated by contact with: concentrated ammonia, arsenic, dinitrogen tetraoxide, hydrogen sulfide, hydrogen trisulfide, nitrogen oxide, organic matter, ozone, phosphine, phosphorus, potassium cyanide, potassium hydroxide solutions, selenium, hydrogen chloride, hydrogen fluoride, hydrogen bromide, hydrogen iodide. Mixtures with chlorine + hydrogen are potentially explosive. Upon decomposition it emits toxic fumes of Cl− and NOx. See also CHLORIDES.
RIDADR: 3099
HazardClass: 5.1
PackingGroup: II
Nitrogen chloride Standards and Recommendations
DOT Classification: Forbidden
Nitrogen chloride Specification
Nitrogen chloride (CAS NO.10025-85-1), its Synonyms are Agene ; Chlorine nitride ; Nitrogen trichloride ; Trichloramine ; Trichlorine nitride ; Nitrogen chloride (NCl3) .
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