Benzyl-phenyl-(1-phenylethylideneamino)amine

Base Information

• Chemical Name: Benzyl-phenyl-(1-phenylethylideneamino)amine
• CAS No.: 1665-84-5
• Molecular Formula: C21H20 N2
• Molecular Weight: 300.403
• NSC Number: 97465
• Mol file: 1665-84-5.mol

Synonyms:MLS002703395;NSC97465;SMR001570114;benzyl-phenyl-(1-phenylethylideneamino)amine;1665-84-5;cid_263125;BDBM94167;NSC-97465;N-benzyl-N-(1-phenylethylideneamino)aniline;N-(1-phenylethylideneamino)-N-(phenylmethyl)aniline

Chemical Property of Benzyl-phenyl-(1-phenylethylideneamino)amine

Chemical Property:

• Vapor Pressure: 3.58E-08mmHg at 25°C
• Boiling Point: 446.7°Cat760mmHg
• Flash Point: 223.9°C
• Density: 1g/cm³
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 300.162648646
• Heavy Atom Count: 23
• Complexity: 358

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NN(CC1=CC=CC=C1)C2=CC=CC=C2)C3=CC=CC=C3
• Isomeric SMILES: C/C(=N\N(CC1=CC=CC=C1)C2=CC=CC=C2)/C3=CC=CC=C3

Technology Process of Benzyl-phenyl-(1-phenylethylideneamino)amine

There total 5 articles about Benzyl-phenyl-(1-phenylethylideneamino)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl chloride (100-44-7) + N-(1-phenylethylidene)phenylhydrazine (583-11-9,59130-82-4) → acetophenone-(benzyl-phenyl-hydrazone) (1665-84-5)

Guidance literature:

N-(1-phenylethylidene)phenylhydrazine; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 0.25h;

benzyl chloride; at 20 ℃; for 5h; Reflux;

DOI:10.1002/anie.201209618

Reference yield:

acetophenone (98-86-2) → acetophenone-(benzyl-phenyl-hydrazone) (1665-84-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: acetic acid / ethanol / 4 h / Reflux

2.1: sodium hydride / tetrahydrofuran / 0.25 h / 0 °C

2.2: 5 h / 20 °C / Reflux

With sodium hydride; acetic acid; In tetrahydrofuran; ethanol;

DOI:10.1002/anie.201209618

Reference yield:

phenylhydrazine (100-63-0) → acetophenone-(benzyl-phenyl-hydrazone) (1665-84-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: acetic acid / ethanol / 4 h / Reflux

2.1: sodium hydride / tetrahydrofuran / 0.25 h / 0 °C

2.2: 5 h / 20 °C / Reflux

With sodium hydride; acetic acid; In tetrahydrofuran; ethanol;

DOI:10.1002/anie.201209618

upstream raw materials:

N-benzyl-N-phenylhydrazine

acetophenone

benzyl chloride

N-(1-phenylethylidene)phenylhydrazine

Downstream raw materials:

2-phenyl-indole

1-benzyl-2-phenyl-1H-indole

1,3,5-triphenyl-1H-pyrazole