methyl 4-(prop-2-en-1-yloxy)benzoate

Base Information

• Chemical Name: methyl 4-(prop-2-en-1-yloxy)benzoate
• CAS No.: 35750-24-4
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol file: 35750-24-4.mol

Synonyms:methyl 4-S-acetyl-2,5-dideoxy-2-methyl-4-thiopent-3-ulosonate;Pentanoic acid,4-(acetylthio)-2-methyl-3-oxo-,methyl ester;1-(4-methoxycarbonylphenyl)-1-phenylmethanol;4-allyloxybenzoic acid methyl ester;(4-methoxycarbonylphenyl)(phenyl)methanol;methyl 4-(acetylsulfanyl)-2-methyl-3-oxopentanoate;methyl 4-(2-propenyloxy)benzoate;methyl 4-(2-propen-1-yl)-oxybenzoate;methyl 4-(3-propenyloxy)benzoate;methyl p-(hydroxy(phenyl)methyl)benzoate;4-acetylsulfanyl-2-methyl-3-oxopentanoic acid methyl ester;methyl 4-allyloxy-benzoate;methyl 4-(a-hydroxybenzyl)benzoate;methyl 4-(hydroxy(phenyl)methyl)benzoate;

Chemical Property of methyl 4-(prop-2-en-1-yloxy)benzoate

Chemical Property:

• Vapor Pressure: 0.00218mmHg at 25°C
• Boiling Point: 289.6oC at 760 mmHg
• Flash Point: 117oC
• PSA: 35.53000
• Density: 1.071g/cm3
• LogP: 2.03800

Purity/Quality:

99% ^*data from raw suppliers

Methyl 4-(allyloxy)benzoate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 4-(prop-2-en-1-yloxy)benzoate

There total 12 articles about methyl 4-(prop-2-en-1-yloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) + 3-chloroprop-1-ene (107-05-1) → methyl 4-allyloxybenzoate (35750-24-4)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃;

Reference yield: 100.0%

methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) + allyl bromide (106-95-6) → methyl 4-allyloxybenzoate (35750-24-4)

Guidance literature:

With potassium carbonate; In acetone; at 65 ℃; for 20h;

DOI:10.1002/anie.201612504

Reference yield: 99.0%

methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) + ethylene dibromide (106-93-4) → methyl 4-allyloxybenzoate (35750-24-4)

Guidance literature:

methyl 4-hydroxylbenzoate; ethylene dibromide; With potassium carbonate; In acetone; for 12h; Inert atmosphere; Reflux;

With potassium tert-butylate; In tetrahydrofuran; for 0.166667h; Inert atmosphere;

DOI:10.3390/molecules25030602

upstream raw materials:

allyl iodid

methyl 4-hydroxylbenzoate

allyl bromide

methanol

Downstream raw materials:

methyl trans-4-<<3-(4-chlorophenyl)-2-methyl-3-<(1H-1,2,4-triazol-1-yl)methyl>isoxazolidin-5-yl>methoxy>benzoate

methyl cis-4-<<3-(4-chlorophenyl)-2-methyl-3-<(1H-1,2,4-triazol-1-yl)methyl>isoxazolidin-5-yl>methoxy>benzoate

4-[(2,2-difluorocyclopropyl)methoxy]benzoic acid

4-allyloxybenzyl alcohol

Refernces

• 1、 -. "DEUTERIUM-ENRICHED SUBSTITUTED PHENOXYPHENYL ACETIC ACIDS AND ACYLSULFONAMIDES". Page/Page column 23; 32. . Retrieved 2021/06/22.
• 2、 Hui, Zi,Jiang, Songwei,Qi, Xiang,Ye, Xiang-Yang,Xie, Tian. "Investigating the microwave-accelerated Claisen rearrangement of allyl aryl ethers: Scope of the catalysts, solvents, temperatures, and substrates". supporting information. . Retrieved 2020/05/18.