Ethene, tetrakis(ethylthio)-

Base Information

• Chemical Name: Ethene, tetrakis(ethylthio)-
• CAS No.: 35994-88-8
• Molecular Formula: C10H20S4
• Molecular Weight: 268.533
• DSSTox Substance ID: DTXSID20404783
• Wikidata: Q82209112
• Mol file: 35994-88-8.mol

Synonyms:Ethene, tetrakis(ethylthio)-;35994-88-8;tetrakis(ethylthio)ethylene;DTXSID20404783;AKOS003245050

Chemical Property of Ethene, tetrakis(ethylthio)-

Chemical Property:

• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 268.04478533
• Heavy Atom Count: 14
• Complexity: 132

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCSC(=C(SCC)SCC)SCC

Technology Process of Ethene, tetrakis(ethylthio)-

There total 5 articles about Ethene, tetrakis(ethylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

diethyl trithiocarbonate (2314-49-0) + ethyl iodide (75-03-6) → diethyl sulphide (352-93-2) + tris(ethylsulfanyl)methane (6267-24-9) + tetrakis(ethylthio)ethene (35994-88-8)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; electrochemical reduction at a mercury pool;

Reference yield: 44.0%

ethyl phenyl trithiocarbonate (77102-69-3) + ethyl iodide (75-03-6) → diethyl sulphide (352-93-2) + tetrakis(ethylthio)ethene (35994-88-8) + Ethyl phenyl sulfide (622-38-8)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; electrochemical reduction at a mercury pool;

Reference yield:

tetrachloromethane (56-23-5) + tris(ethylsulfanyl)methane (6267-24-9) → Diethyl disulfide (110-81-6) + chloroethane (75-00-3) + chloroform (67-66-3,8013-54-5) + hexachloroethane (67-72-1) + diethyl trithiocarbonate (2314-49-0) + tetrakis(ethylthio)ethene (35994-88-8)

Guidance literature:

With di-tert-butyl peroxide; at 150 ℃; for 1h; Product distribution; Mechanism;

upstream raw materials:

tetrachloromethane

tris(ethylsulfanyl)methane

diethyl trithiocarbonate

ethyl iodide

Downstream raw materials:

diethyl sulphide

1,2-bis-ethylsulfanyl-tetrachloro-ethane

fac-tricarbonyl[tetrakis(ethylthio)ethene-S,S''](triphenylphosphine)chromium⁽⁰⁾

fac-[W(CO)3(PPh₃)(C₂(SEt)4)]