Benzenepropanoic acid, a-nitro-, methyl ester

Base Information

Chemical Name:Benzenepropanoic acid, a-nitro-, methyl ester
CAS No.:40149-56-2
Molecular Formula:C10H11NO4
Molecular Weight:209.202
Hs Code.:

Synonyms:2-Nitro-3-phenyl-propionic acid methyl ester;methyl 2-nitro-3-phenyl propanoate;methyl 2-nitro-3-phenylpropionate;α-Nitro-β-phenyl-propionsaeuremethylester;α-Nitro-β-phenylpropionsaeuremethylester;

Suppliers and Price of Benzenepropanoic acid, a-nitro-, methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzenepropanoic acid, a-nitro-, methyl ester

Chemical Property:

Melting Point:37.0-37.8 °C(Solv: chloroform (67-66-3); hexane (110-54-3))
Boiling Point:128 - 130 °C (1 mmHg)
PSA：72.12000
Density:1.216±0.06 g/cm3(Predicted)
LogP:1.57060

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzenepropanoic acid, a-nitro-, methyl ester

There total 14 articles about Benzenepropanoic acid, a-nitro-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 15028-44-1
DL-phenylalanine methyl ester

: 40149-56-2
Methyl α-nitro-β-phenylpropionate

Guidance literature:: With HOF* CH₃CN; sodium fluoride; In dichloromethane; water; acetonitrile; for 0.0833333h; Ambient temperature;
DOI:10.1021/jo00084a047

Reference yield: 70.0%

: 2483-57-0
methyl 2-nitroacetate

: 100-39-0
benzyl bromide

: 40149-56-2
Methyl α-nitro-β-phenylpropionate

: 114858-58-1
C₁₀H₁₁NO₄

: 114858-59-2
2-[(E)-Benzyloxyimino]-3-phenyl-propionic acid methyl ester

Guidance literature:: With N-benzyl-N,N,N-triethylammonium chloride; potassium hydrogencarbonate; In N,N-dimethyl-formamide; at 60 ℃; for 16h;

Reference yield: 35.0%

: 2483-57-0
methyl 2-nitroacetate

: 100-52-7
benzaldehyde

: 40149-56-2
Methyl α-nitro-β-phenylpropionate

Guidance literature:: methyl 2-nitroacetate; benzaldehyde; With titanium tetrachloride; In tetrahydrofuran; tetrachloromethane; at 0 ℃; for 2h;

With 4-methyl-morpholine; In tetrahydrofuran; tetrachloromethane; at 18 ℃; for 20h;

With sodium tetrahydroborate; silica gel; In chloroform; isopropyl alcohol; at 20 ℃; for 4h;
DOI:10.1021/ja0343151