Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl-

Base Information

• Chemical Name: Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl-
• CAS No.: 55991-65-6
• Molecular Formula: C12H18O2Si
• Molecular Weight: 222.359
• DSSTox Substance ID: DTXSID90452630
• Nikkaji Number: J579.850G
• Wikidata: Q82273380
• Mol file: 55991-65-6.mol

Synonyms:55991-65-6;Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl-;SCHEMBL8215216;DTXSID90452630;4-[1-(Trimethylsiloxy)ethenyl]anisole;((1-(4-methoxyphenyl)vinyl)oxy)trimethylsilane

Chemical Property of Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 222.107606347
• Heavy Atom Count: 15
• Complexity: 212

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(=C)O[Si](C)(C)C

Technology Process of Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl-

There total 6 articles about Silane, [[1-(4-methoxyphenyl)ethenyl]oxy]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

chloro-trimethyl-silane (75-77-4) + 1-(4-methoxyphenyl)ethanone (100-06-1) → [1-(4-methoxyphenyl)vinyloxy]trimethylsilane (55991-65-6)

Guidance literature:

With triethylamine; In acetonitrile; at -5 - 0 ℃; Inert atmosphere;

DOI:10.2174/1570178614666161205161634

Reference yield: 80.0%

4-methoxy-benzaldehyde (123-11-5) + diazomethyl-trimethyl-silane (18107-18-1) → [1-(4-methoxyphenyl)vinyloxy]trimethylsilane (55991-65-6) + cis-1-(4-methoxyphenyl)-2-(trimethylsilyloxy)ethylene + trans-1-(4-methoxyphenyl)-2-(trimethylsilyloxy)ethylene

Guidance literature:

With {[pyridine-2,6-(2,6-iPr₂Ph-N=C(CH₃))2]Rh(I)}⁽¹⁺⁾; In dichloromethane;

DOI:10.1021/ja003608g

Reference yield: 59.0%

trimethylsilyl trifluoromethanesulfonate (27607-77-8) + 1-(4-methoxyphenyl)ethanone (100-06-1) → [1-(4-methoxyphenyl)vinyloxy]trimethylsilane (55991-65-6)

Guidance literature:

With triethylamine; In diethyl ether; at 0 - 20 ℃; for 2.25h;

DOI:10.1039/b104340b

upstream raw materials:

chloro-trimethyl-silane

1-(4-methoxyphenyl)ethanone

trimethylsilyl trifluoromethanesulfonate

4-methoxy-benzaldehyde

Downstream raw materials:

1-(trimethylsilyloxy)1-(4-methoxyphenyl)cyclopropane

(E)-2-tert-Butyl-5-(4-methoxy-phenyl)-5-oxo-3-trimethylsilanyloxy-pent-2-enenitrile

7-(4-Methoxy-phenyl)-6-oxa-spiro[3.5]non-7-ene-5,9-dione

C₁₈H₂₃NO₃Si