1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane

Base Information

• Chemical Name: 1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane
• CAS No.: 57519-88-7
• Molecular Formula: C9H14Cl2Si2
• Molecular Weight: 249.287
• DSSTox Substance ID: DTXSID10453942
• Nikkaji Number: J877.297E
• Wikidata: Q82275242
• Mol file: 57519-88-7.mol

Synonyms:57519-88-7;1,1-DICHLORO-2,2,2-TRIMETHYL-1-PHENYLDISILANE;SCHEMBL9053522;DTXSID10453942;1,1,1-Trimethyl-2,2-dichloro-2-phenyldisilane

Chemical Property of 1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 248.0011089
• Heavy Atom Count: 13
• Complexity: 169

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)[Si](C1=CC=CC=C1)(Cl)Cl

Technology Process of 1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane

There total 6 articles about 1,1-Dichloro-2,2,2-trimethyl-1-phenyldisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

1,1,1-trimethyl-2,2,2-triphenyldisilane (1450-18-6) → 1,1,1-trichloro-2,2,2-trimethyldisilane (18026-87-4) + 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane (57519-88-7)

Guidance literature:

With hydrogenchloride; aluminium trichloride; In benzene; for 4h;

DOI:10.1016/S0040-4020(01)80758-4

Reference yield:

tetrachloromethane (56-23-5) + tris(trimethylsilyl)phenylsilane (4235-65-8) → chloro-trimethyl-silane (75-77-4) + 1,1,1,2,2,2-hexamethyldisilane (1450-14-2) + hexachloroethane (67-72-1) + 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane (57519-88-7) + chlorobis(trimethylsilyl)phenylsilane (127348-36-1)

Guidance literature:

In pentane; for 2h; Product distribution; Mechanism; Irradiation; var. times; other alkyl chlorides;

DOI:10.1016/0022-328X(90)85076-B

Reference yield:

Triphenylsilyl chloride (76-86-8) → 1,1-dichloro-1-phenyl-2,2,2-trimethyldisilane (57519-88-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 77 percent / lithium / tetrahydrofuran / 20 h / Ambient temperature

2: 75 percent / hydrogen chloride, aluminium chloride / benzene / 4 h

With hydrogenchloride; aluminium trichloride; lithium; In tetrahydrofuran; benzene;

DOI:10.1016/S0040-4020(01)80758-4

upstream raw materials:

1,1,1-trimethyl-2,2,2-triphenyldisilane

tetrachloromethane

tris(trimethylsilyl)phenylsilane

Triphenylsilyl chloride

Downstream raw materials:

4-(dimethyl-phenyl-silanyl)-butan-2-one

1-methoxy-1-phenyl-3,4-dimethyl-1-silacyclopent-3-ene

(2RS,3RS)-3-dimethyl(phenyl)silyl-2-methyl-1,3-diphenylpropan-1-one

syn-2-methyl-1,3-diphenyl-3-(phenyldimethylsilyl)-1-propanone