Triethoxy(hex-1-EN-1-YL)silane

Base Information

• Chemical Name: Triethoxy(hex-1-EN-1-YL)silane
• CAS No.: 62621-32-3
• Molecular Formula: C12H26O3Si
• Molecular Weight: 246.422
• DSSTox Substance ID: DTXSID70706623
• Mol file: 62621-32-3.mol

Synonyms:62621-32-3;TRIETHOXY(HEX-1-EN-1-YL)SILANE;DTXSID70706623

Chemical Property of Triethoxy(hex-1-EN-1-YL)silane

Chemical Property:

• PSA: 27.69000
• LogP: 3.32040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 10
• Exact Mass: 246.16512122
• Heavy Atom Count: 16
• Complexity: 166

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=C[Si](OCC)(OCC)OCC

Technology Process of Triethoxy(hex-1-EN-1-YL)silane

There total 2 articles about Triethoxy(hex-1-EN-1-YL)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Triethoxysilane (998-30-1) + hex-1-yne (693-02-7) → 1-hexene (592-41-6,25067-06-5) + 2-(triethoxylsilyl)-1-hexene (59549-88-1) + trans-1-(triethoxylsilyl)-1-hexene (62621-32-3) + cis-1-(triethoxylsilyl)-1-hexene

Guidance literature:

With [RhCl(triphenylphosphine){P(OC₆H₄NMe)OC₆H₄NHMe}]; In toluene; at 75 ℃; for 5h; Glovebox; Inert atmosphere;

DOI:10.1016/j.ica.2017.04.065

Reference yield:

1-hexene (592-41-6,25067-06-5) + Triethoxyvinylsilane (78-08-0) → ethene (74-85-1) + 5-decene (19689-19-1) + trans-1-(triethoxylsilyl)-1-hexene (62621-32-3) + cis-1-(triethoxylsilyl)-1-hexene

Guidance literature:

Grubbs catalyst first generation; In dichloromethane; for 3h; Further Variations:; Reaction partners; reaction time; Product distribution; Heating;

DOI:10.1016/S0040-4039(00)02201-2

Reference yield:

trans-1-(triethoxylsilyl)-1-hexene (62621-32-3) + dibutylamine (111-92-2) → 1-hexene (592-41-6,25067-06-5) + N-(triethoxysilyl)dibutylamine

Guidance literature:

With carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II); In toluene; at 120 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c4dt03084b

upstream raw materials:

1-hexene

Triethoxyvinylsilane

Triethoxysilane

hex-1-yne

Downstream raw materials:

1-hexene

N-(triethoxysilyl)diethylamine

Refernces

• 1、 Pietraszuk, Cezary,Fischer, Helmut,Kujawa, Malgorzata,Marciniec, Bogdan. "Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs' catalyst". . p. 1175 - 1178. Retrieved 2007/10/03.