Dichloro(fluoro)alumane

Base Information

• Chemical Name: Dichloro(fluoro)alumane
• CAS No.: 13497-96-6
• Molecular Formula: AlCl₂F
• Molecular Weight: 116.886
• DSSTox Substance ID: DTXSID201293109
• Mol file: 13497-96-6.mol

Synonyms:dichloro(fluoro)alumane;Aluminum chloride fluoride;13497-96-6;Aluminum chloride fluoride (AlCl2F);AlCl2F;DTXSID201293109

Chemical Property of Dichloro(fluoro)alumane

Chemical Property:

• Vapor Pressure: 922mmHg at 25°C
• Boiling Point: 19.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -8.65050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 115.9176470
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: F[Al](Cl)Cl

Technology Process of Dichloro(fluoro)alumane

There total 4 articles about Dichloro(fluoro)alumane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrachloromethane (56-23-5) + Carbonyl fluoride (353-50-4) → monofluorodichloroaluminum (13497-96-6) + carbon tetrafluoride (75-73-0) + chlorotrifluoromethane (75-72-9) + Dichlorodifluoromethane (75-71-8) + trichlorofluoromethane (75-69-4)

Guidance literature:

aluminium trichloride; 300°C;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + aluminum(I) fluoride → monofluorodichloroaluminum (13497-96-6) + AlF2Cl (13814-65-8) + AlFClH (473252-05-0)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); UV photolysis (254 nm)in Ar matrix; not isolated, identified by IR;

DOI:10.1021/ic020275a

Reference yield:

aluminum(I) fluoride + hydrogen chloride (7698-05-7) → monofluorodichloroaluminum (13497-96-6) + AlF2Cl (13814-65-8) + (2)HAlFCl (473252-10-7)

Guidance literature:

In neat (no solvent); Irradiation (UV/VIS); UV photolysis (254 nm)in Ar matrix; not isolated, identified by IR;

DOI:10.1021/ic020275a

upstream raw materials:

aluminium trichloride

Carbonyl fluoride

tetrachloromethane

hydrogenchloride

Refernces