Methyl cis-9-tetradecenoate

Base Information

• Chemical Name: Methyl cis-9-tetradecenoate
• CAS No.: 56219-06-8
• Molecular Formula: C15H28 O2
• Molecular Weight: 240.386
• UNII: M2A58GY964
• DSSTox Substance ID: DTXSID001346982
• Nikkaji Number: J47.544K
• Wikidata: Q27283392
• Metabolomics Workbench ID: 4138
• Mol file: 56219-06-8.mol

Synonyms:methyl myristoleate

Chemical Property of Methyl cis-9-tetradecenoate

Chemical Property:

• Appearance/Colour: liquid
• Vapor Pressure: 0.000763mmHg at 25°C
• Melting Point: 52.2℃
• Refractive Index: n20/D 1.446
• Boiling Point: 306.6 °C at 760 mmHg
• Flash Point: 90.9 °C
• PSA: 26.30000
• Density: 0.879 g/cm³
• LogP: 4.63650
• Storage Temp.: −20°C
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 240.208930132
• Heavy Atom Count: 17
• Complexity: 197

Purity/Quality:

99.9% ^*data from raw suppliers

MyristoleicAcidMethylEster ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCC=CCCCCCCCC(=O)OC
• Isomeric SMILES: CCCC/C=C\CCCCCCCC(=O)OC
• Uses: Myristoleic Acid methyl ester is a cytotoxic inducer of apoptosis and necrosis. Methyl myristoleate can be used in medical research andorganic synthesis.

Technology Process of Methyl cis-9-tetradecenoate

There total 6 articles about Methyl cis-9-tetradecenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) → methyl (7Z,10Z,13Z,16Z,19Z)-docosa-7,10,13,16,19-pentaenoate (108698-02-8) + methyl vaccenate (1937-63-9,52380-33-3,6198-58-9) + methyl linoleate (16326-32-2) + methyl arachidonate (2566-89-4) + (Z)-9-hexadecenoic acid methyl ester (1120-25-8,3913-63-1) + Methyl oleate (112-62-9) + Methyl linoleate (112-63-0) + (11Z)-11-icosenoic acid methyl ester (2390-09-2,3946-08-5) + methyl linolenate (301-00-8) + methyl n-dodecanoate (111-82-0) + methyl myristoate (124-10-7) + pentadecanoic acid methyl ester (7132-64-1) + hexadecanoic acid methyl ester (112-39-0) + methyl margarate (1731-92-6) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + behenic acid methyl ester (929-77-1) + all-cis-8,11,14-eicosatrienoic acid methyl ester (21061-10-9) + (5Z,8Z,11Z,14Z,17Z)-5,8,11,14,17-icosapentaenoic acid methyl ester (2734-47-6) + cis,cis,cis,cis-Docosa-7,10,13,16-tetraensaeuremethylester (13487-42-8) + myristoleic acid methyl ester (56219-06-8) + cis,trans-9,11-methyloctadecadienoate (35042-75-2)

Guidance literature:

With potassium hydroxide; water; In methanol; at 55 ℃; for 1.5h;

methanol; With sulfuric acid; In water; at 20 - 55 ℃; for 1.5h; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + sodium methylate (124-41-4) → methyl (7Z,10Z,13Z,16Z,19Z)-docosa-7,10,13,16,19-pentaenoate (108698-02-8) + methyl vaccenate (1937-63-9,52380-33-3,6198-58-9) + methyl linoleate (16326-32-2) + methyl arachidonate (2566-89-4) + (Z)-9-hexadecenoic acid methyl ester (1120-25-8,3913-63-1) + Methyl oleate (112-62-9) + Methyl linoleate (112-63-0) + (11Z)-11-icosenoic acid methyl ester (2390-09-2,3946-08-5) + methyl linolenate (301-00-8) + methyl n-dodecanoate (111-82-0) + methyl myristoate (124-10-7) + pentadecanoic acid methyl ester (7132-64-1) + hexadecanoic acid methyl ester (112-39-0) + methyl margarate (1731-92-6) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + behenic acid methyl ester (929-77-1) + all-cis-8,11,14-eicosatrienoic acid methyl ester (21061-10-9) + (5Z,8Z,11Z,14Z,17Z)-5,8,11,14,17-icosapentaenoic acid methyl ester (2734-47-6) + cis,cis,cis,cis-Docosa-7,10,13,16-tetraensaeuremethylester (13487-42-8) + myristoleic acid methyl ester (56219-06-8) + cis,trans-9,11-methyloctadecadienoate (35042-75-2)

Guidance literature:

at 55 ℃; for 1.5h; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + fish oil → methyl (7Z,10Z,13Z,16Z,19Z)-docosa-7,10,13,16,19-pentaenoate (108698-02-8) + methyl linoleate (16326-32-2) + all-cis-4,7,10,13,16,19-docosahexaenoic acid methyl ester (2566-90-7,875288-77-0) + (Z)-9-hexadecenoic acid methyl ester (1120-25-8,3913-63-1) + Methyl oleate (112-62-9) + Methyl linoleate (112-63-0) + (11Z)-11-icosenoic acid methyl ester (2390-09-2,3946-08-5) + methyl linolenate (301-00-8) + methyl cis-tetracos-15-enate (2733-88-2) + methyl n-dodecanoate (111-82-0) + methyl myristoate (124-10-7) + hexadecanoic acid methyl ester (112-39-0) + methyl margarate (1731-92-6) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + (5Z,8Z,11Z,14Z,17Z)-5,8,11,14,17-icosapentaenoic acid methyl ester (2734-47-6) + myristoleic acid methyl ester (56219-06-8) + methyl (13Z,16Z)-docosadienoate (61012-47-3) + (11Z,14Z)-11,14-icosadienoic acid methyl ester (61012-46-2) + cis-10-heptadecenoic acid methyl ester (369657-02-3,75190-82-8)

Guidance literature:

fish oil; With potassium hydroxide; water; In methanol; at 55 ℃; for 1.5h;

methanol; With sulfuric acid; In water; at 20 - 55 ℃; for 1.5h; Product distribution / selectivity;

upstream raw materials:

methanol

sodium methylate

Downstream raw materials:

cis-9-cetyl myristoleate

(Z)-9-tetradecen-1-yl acetate

(Z)-9-tetradecen-1-ol

Refernces

• 1、 Seki, Katsura,Tomihari, Toshiya,Haga, Kazuo,Kaneko, Ryohei. "IRISTECTORENES A AND C-G, MONOCYCLIC TRITERPENE ESTERS FROM IRIS TECTORUM". . p. 425 - 432. Retrieved 2007/10/02.