Vinyl acrylate

Base Information

• Chemical Name: Vinyl acrylate
• CAS No.: 2177-18-6
• Molecular Formula: C5H6 O2
• Molecular Weight: 98.1014
• Hs Code.: 2915320000
• European Community (EC) Number: 218-538-1
• NSC Number: 4768
• UNII: YA7T88HHM8
• DSSTox Substance ID: DTXSID1073286
• Nikkaji Number: J100.705J
• Wikidata: Q65225727
• Mol file: 2177-18-6.mol

Synonyms:Vinyl acrylate;2177-18-6;Acrylic acid, vinyl ester;2-Propenoic acid, ethenyl ester;Ethenyl 2-propenoate;Acrylic acid vinyl ester;ethenyl prop-2-enoate;YA7T88HHM8;CCRIS 7746;NSC-4768;EINECS 218-538-1;30811-69-9;vinylacrylate;Vinyl acrylate contains;UNII-YA7T88HHM8;DTXSID1073286;BLCTWBJQROOONQ-UHFFFAOYSA-;NSC4768;NSC 4768;MFCD00059325;Acrylic acid, vinyl ester (6CI,7CI,8CI);LS-123636;FT-0621883;Q65225727;Vinyl acrylate, contains <600 ppm MEHQ as inhibitor

Chemical Property of Vinyl acrylate

Chemical Property:

• Vapor Pressure: 53.7mmHg at 25°C
• Melting Point: -81.9°C
• Refractive Index: n20/D 1.432(lit.)
• Boiling Point: 91.5°Cat760mmHg
• Flash Point: 13.5°C
• PSA: 26.30000
• Density: 0.936g/cm³
• LogP: 0.85910
• Storage Temp.: 2-8°C
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 98.036779430
• Heavy Atom Count: 7
• Complexity: 94.3

Purity/Quality:

99% ^*data from raw suppliers

Vinyl acrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison by ingestion. Low toxicity by inhalation. A severe skin and eye irritant.
• Hazard Codes: F,T,T+
• Statements: 11-25-34-41-38-28-20
• Safety Statements: 9-16-26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OC=C
• Uses: This acrylate monomer has a vinyl group for functionalization. It can also be used as a crosslinkable monomer.

Technology Process of Vinyl acrylate

There total 7 articles about Vinyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

vinyl β-chloropropionate (5309-67-1) → vinyl acrylate (2177-18-6,30811-69-9)

Guidance literature:

With sodium methylate; In methanol; at 50 - 55 ℃;

Reference yield:

ethene (74-85-1) + acrylic acid (79-10-7) → α-methylene-γ-butyrolactone (547-65-9) + vinyl acrylate (2177-18-6,30811-69-9)

Guidance literature:

With oxygen; sodium 2-propenoate; p-benzoquinone; palladium diacetate; In 1-methyl-pyrrolidin-2-one; at 50 - 60 ℃; for 4 - 36h; under 1838.93 - 2942.29 Torr; Product distribution / selectivity;

Reference yield:

acrylic acid (79-10-7) + acetylene (74-86-2,25067-58-7) → vinyl acrylate (2177-18-6,30811-69-9)

Guidance literature:

decacarbonyldirhenium⁽⁰⁾; In toluene; at 140 ℃; for 17h; under 15001.5 Torr; Product distribution / selectivity;

upstream raw materials:

vinyl acetate

acrylic acid

divinylmercury

vinyl β-chloropropionate

Downstream raw materials:

2-phenylethyl acrylate

(formylmethyl)mercury chloride

acrylic acid

vinyl β-chloropropionate

Refernces

• 1、 -. "METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND". Page/Page column 75-76, 84-85; 91; 93. . Retrieved 2008/06/13.
• 2、 -. "Transvinylation process for the preparation of thermally labile vinyl compounds and for vinyl compounds prepared from thermally labile acids". . . Retrieved 2008/06/13.