hydroperoxymethanol

Base Information

• Chemical Name: hydroperoxymethanol
• CAS No.: 15932-89-5
• Molecular Formula: CH4 O3
• Molecular Weight: 64.041
• Mol file: 15932-89-5.mol

Synonyms:Hydroperoxide,hydroxymethyl (6CI); Hydroxymethyl hydroperoxide

Chemical Property of hydroperoxymethanol

Chemical Property:

• Vapor Pressure: 0.000192mmHg at 25°C
• Boiling Point: 292.7°C at 760 mmHg
• Flash Point: 130.8°C
• Density: 1.379g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of hydroperoxymethanol

There total 15 articles about hydroperoxymethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.2%

ethane (74-84-0) → peracetic acid (79-21-0) + methyl hydroperoxide (3031-73-0) + ethyl hydroperoxide (3031-74-1) + hydroxymethylhydroperoxide (15932-89-5)

Guidance literature:

With nitrogen; oxygen; chlorine; at 24.85 ℃; for 0.5h; under 760 Torr; Kinetics; Photolysis;

DOI:10.1016/S0045-6535(98)00517-7

Reference yield: 3.39%

propane (74-98-6) → peracetic acid (79-21-0) + methyl hydroperoxide (3031-73-0) + ethyl hydroperoxide (3031-74-1) + hydroxymethylhydroperoxide (15932-89-5)

Guidance literature:

With nitrogen; oxygen; chlorine; at 24.85 ℃; for 0.333333h; under 760 Torr; Kinetics; Photolysis;

DOI:10.1016/S0045-6535(98)00517-7

Reference yield: 0.95%

1-methylcyclohex-1-ene (591-49-1) → peracetic acid (79-21-0) + methyl hydroperoxide (3031-73-0) + hydroxymethylhydroperoxide (15932-89-5)

Guidance literature:

With ozone; under 787.563 Torr; Product distribution;

DOI:10.1246/cl.2001.1248

upstream raw materials:

methanol

bis-hydroxymethyl peroxide

hydroxymethylperoxyl radical

ascorbate

Downstream raw materials:

formaldehyd

formic acid

methanediol

Refernces

• 1、 Zhou, Xianliang,Lee, Yin-Nan. "Aqueous Solubility and Reaction Kinetics of Hydroxymethyl Hydroperoxide". . p. 265 - 272. Retrieved 1992.
• 2、 Yu, Tao,Su, Yang,Wang, Aiqin,Weckhuysen, Bert M.,Luo, Wenhao. "Efficient Synthesis of Monomeric Fe Species in Zeolite ZSM-5 for the Low-Temperature Oxidation of Methane". . p. 2766 - 2770. Retrieved 2021.
• 3、 Zhao, Wenshi,Shi, Yanan,Jiang, Yuheng,Zhang, Xiaofei,Long, Chang,An, Pengfei,Zhu, Yanfei,Shao, Shengxian,Yan, Zhuang,Li, Guodong,Tang, Zhiyong. "Fe-O Clusters Anchored on Nodes of Metal–Organic Frameworks for Direct Methane Oxidation". supporting information. p. 5811 - 5815. Retrieved 2021/02/06.