Ethyl hydroperoxide

Base Information

• Chemical Name: Ethyl hydroperoxide
• CAS No.: 3031-74-1
• Molecular Formula: C2H6 O2
• Molecular Weight: 62.0684
• Hs Code.: 2909600000
• European Community (EC) Number: 221-211-6
• UNII: 08608DV9AD
• DSSTox Substance ID: DTXSID70184402
• Nikkaji Number: J78.040E
• Wikipedia: Ethyl_hydroperoxide
• Wikidata: Q27236368,Q82932544
• Mol file: 3031-74-1.mol

Synonyms:ethyl hydroperoxide

Chemical Property of Ethyl hydroperoxide

Chemical Property:

• Vapor Pressure: 27.4mmHg at 25°C
• Melting Point: -100°C
• Refractive Index: 1.3640 (estimate)
• Boiling Point: 95°Cat760mmHg
• PKA: pK1:11.80 (25°C)
• Flash Point: 11.3°C
• PSA: 29.46000
• Density: 0.948g/cm³
• LogP: 0.49590
• XLogP3: 0
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 62.036779430
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Peroxides, Organic
• Canonical SMILES: CCOO

Technology Process of Ethyl hydroperoxide

There total 40 articles about Ethyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diperoxyterephthalic acid diethyl ester (108991-57-7) + water (7732-18-5) → ethyl hydroperoxide (3031-74-1) + terephthalic acid (100-21-0)

Guidance literature:

Reference yield:

diperoxyterephthalic acid diethyl ester (108991-57-7) → ethyl hydroperoxide (3031-74-1) + terephthalic acid (100-21-0)

Guidance literature:

Reference yield:

ethane (74-84-0) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + ethene (74-85-1) + ethyl hydroperoxide (3031-74-1) + acetaldehyde (75-07-0,9002-91-9)

Guidance literature:

With nitrogen; oxygen; chlorine; at 298 ℃; for 4h; under 700 Torr; Product distribution; Irradiation;

DOI:10.1021/j100216a023

upstream raw materials:

diethyl sulfate

ethane

ethylmagnesium chloride

azoethane

Downstream raw materials:

ethyl nitrate

methoxyethylether

ethylperoxy radical

benzoic acid ethyl ester

Refernces

• 1、 Kaiser, E. W.. "Temperature and pressure Dependence of the C2H4 Yield from the Reaction C2H5 + O2". . p. 707 - 711. Retrieved 1995.
• 2、 Fenter, Frederick F.,Catoire, Valery,Lesclaux, Robert,Lightfoot, Phillip D.. "The Ethylperoxy Radical: Its Ultraviolet Spectrum, Self-Reaction, and Reaction with HO2, Each Studied as a Function of Temperature". . p. 3530 - 3538. Retrieved 1993.
• 3、 Akiba,Simamura. "". . p. 2527,2529,2530. Retrieved 1970.
• 4、 Maricq, M. Matti,Szente, Joseph J.. "A Kinetic Study of the Reaction between Ethylperoxy Radicals and HO2". . p. 2078 - 2082. Retrieved 1994.
• 5、 Clay, Mary,Ault, Bruce S.. "Infrared matrix isolation and theoretical study of the initial intermediates in the reaction of ozone with cis-2-Butene". . p. 2799 - 2805. Retrieved 2010.
• 6、 Ahmad,Clay. "-". . p. 845. Retrieved 1966.
• 7、 Felvey, Noah,Gurses, Sadi,Kronawitter, Coleman X.,Wang, Yu Lei. "Room temperature and atmospheric pressure aqueous partial oxidation of ethane to oxygenates over AuPd catalysts". . p. 6679 - 6686. Retrieved 2020/11/16.
• 8、 Sutradhar, Manas,Shvydkiy, Nikita V.,Guedes Da Silva, M. Fátima C.,Kirillova, Marina V.,Kozlov, Yuriy N.,Pombeiro, Armando J. L.,Shul'Pin, Georgiy B.. "A new binuclear oxovanadium(v) complex as a catalyst in combination with pyrazinecarboxylic acid (PCA) for efficient alkane oxygenation by H 2O2". supporting information. p. 11791 - 11803. Retrieved 2013/09/02.