Monochlorodisilane

Base Information

• Chemical Name: Monochlorodisilane
• CAS No.: 14565-98-1
• Molecular Formula: ClH5Si2
• Molecular Weight: 96.6637
• European Community (EC) Number: 810-623-7
• Nikkaji Number: J149.785E
• Wikidata: Q17337578
• Mol file: 14565-98-1.mol

Synonyms:monochlorodisilane;FXMNVBZEWMANSQ-UHFFFAOYSA-N;Q17337578

Chemical Property of Monochlorodisilane

Chemical Property:

• PSA: 0.00000
• LogP: -1.41060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 95.9618309
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [SiH3][SiH2]Cl

Technology Process of Monochlorodisilane

There total 3 articles about Monochlorodisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

disilane (1590-87-0) + boron trichloride (10294-34-5) → monochlorodisilane (14565-98-1)

Guidance literature:

In neat (no solvent); at 0°C for 8 h; fractionated distn. at -63°C, -96°C, product collected at -196°C;

DOI:10.1016/0584-8539(91)80123-Z

Reference yield:

monochlorosilylene (13931-97-0,13465-78-6) + monosilane (7440-21-3) → monochlorodisilane (14565-98-1)

Guidance literature:

In gaseous matrix; room temp., SiCl2H2/ SiH4/ N2 total pressure 500 Torr; Kinetics;

DOI:10.1016/0009-2614(86)80639-X

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + disilane (1590-87-0) → monochlorodisilane (14565-98-1) + dichloro disilane

Guidance literature:

In neat (no solvent); reaction of HCl with Si2H6 (1 vol.:>1 vol.);; impure;;

upstream raw materials:

disilane

boron trichloride

monochlorosilylene

monosilane

Downstream raw materials:

hydrogenchloride

1.2-bis-(monosilyl)-disiloxane

Refernces