Silylene, chloro-

Base Information

• Chemical Name: Silylene, chloro-
• CAS No.: 13931-97-0
• Molecular Formula: ClHSi
• Molecular Weight: 64.5464
• Mol file: 13931-97-0.mol

Synonyms:

Chemical Property of Silylene, chloro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silylene, chloro-

There total 4 articles about Silylene, chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trichlorosilane (10025-78-2) + sulfur trioxide (7446-11-9) → chlorosulfonic acid (7790-94-5) + pyrosulfuryl chloride (7791-27-7) + monochlorosilylene (13931-97-0,13465-78-6) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3)

Guidance literature:

In neat (no solvent); slow reaction in the cold; explosive reaction on heating at 100°C in a sealed tube;; distillation;;

Reference yield:

1-chloro-1-silacyclopent-3-ene (55544-26-8) → monochlorosilylene (13931-97-0,13465-78-6)

Guidance literature:

In gas; Irradiation (UV/VIS); ClSiH produced by flash photolysis of 1-chlorosilacyclopent-3-ene at 299K using an exciplex laser operating at 193 nm; not isolated, detected by laser spectroscopy;

DOI:10.1016/j.cplett.2005.07.079

Reference yield:

Dichlorosilane (4109-96-0) → monochlorosilylene (13931-97-0,13465-78-6)

Guidance literature:

In gaseous matrix; excimer laser photolysis; not isolated, LEF;

DOI:10.1016/0009-2614(86)80639-X

upstream raw materials:

trichlorosilane

sulfur trioxide

1-chloro-1-silacyclopent-3-ene

Dichlorosilane

Downstream raw materials:

monochlorodisilane