Trimethylsilyl=cyclohexanecarboxylate

Base Information

• Chemical Name: Trimethylsilyl=cyclohexanecarboxylate
• CAS No.: 69435-89-8
• Molecular Formula: C10H20O2Si
• Molecular Weight: 200.353
• Mol file: 69435-89-8.mol

Synonyms:Cyclohexanecarboxylic acid,trimethylsilyl ester;

Chemical Property of Trimethylsilyl=cyclohexanecarboxylate

Chemical Property:

• PSA: 26.30000
• LogP: 2.94480

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Trimethylsilyl=cyclohexanecarboxylate

There total 5 articles about Trimethylsilyl=cyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) + Cyclohexanecarboxylic acid (98-89-5) → trimethylsilyl cyclohexanecarboxylate (69435-89-8)

Guidance literature:

In neat (no solvent); at 20 ℃; for 96h; Green chemistry;

DOI:10.1016/j.tet.2016.08.003

Reference yield: 70.0%

Hexamethyldisiloxane (107-46-0) + Cyclohexanecarboxylic acid (98-89-5) → trimethylsilyl cyclohexanecarboxylate (69435-89-8)

Guidance literature:

With sulfuric acid; In toluene; for 90h; Heating;

DOI:10.1246/cl.1980.1475

Reference yield:

methyl cyclohexylcarboxylate (4630-82-4) + N,N-diethyl-1,1,1-trimethylsilanamine (996-50-9) → trimethylsilyl cyclohexanecarboxylate (69435-89-8)

Guidance literature:

With methyl iodide; In toluene; at 95 - 115 ℃; for 75h;

DOI:10.1016/0022-328X(95)05822-7

upstream raw materials:

chloro-trimethyl-silane

methyl cyclohexylcarboxylate

Hexamethyldisiloxane

Cyclohexanecarboxylic acid

Downstream raw materials:

(Z)-1-cyclohexyl-1-(trimethylsilyloxy)-1-propene

cyclohexyl-3-methyl-4-methoxyphenyl ketone

((Z)-1-Cyclohexyl-3-phenyl-propenyloxy)-trimethyl-silane

3-phenylpropyl cyclohexanecarboxylate