1-Methyl-1-silacyclobutane

Base Information

Chemical Name:1-Methyl-1-silacyclobutane
CAS No.:765-33-3
Molecular Formula:C4H10Si
Molecular Weight:86.2089
Hs Code.:
DSSTox Substance ID:DTXSID90338162
Mol file:765-33-3.mol

Synonyms:1-Methyl-1-silacyclobutane;Silacyclobutane, 1-methyl-;765-33-3;methylsilacyclobutane;1-Methylsiletane #;DTXSID90338162;CQFRXHDORNUERA-UHFFFAOYSA-N

Suppliers and Price of 1-Methyl-1-silacyclobutane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 13 raw suppliers

Chemical Property of 1-Methyl-1-silacyclobutane

Chemical Property:

PSA：0.00000
LogP:1.24700
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:85.047351822
Heavy Atom Count:5
Complexity:30.6

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si]1CCC1
General Description 1-Methylsiletane (1-methylsilacyclobutane) exists in two conformers, axial and equatorial, with the equatorial form being more stable by an enthalpy difference of 1.46 ± 0.32 kJ/mol. The Si-H bond distance was determined to be 1.490 ? for both conformers. Vibrational assignments for the equatorial conformer were established using infrared and Raman spectroscopy, supported by normal coordinate analysis and ab initio calculations. The axial conformer's fundamentals were also identified, though a polycrystalline solid with a single conformer could not be isolated. The molecular geometries of both conformers were optimized using ab initio methods with 3-21G* and 6-31G* basis sets.

Technology Process of 1-Methyl-1-silacyclobutane

There total 5 articles about 1-Methyl-1-silacyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 2351-34-0
1-chloro-1-methylsiletane

: 765-33-3
1-methyl-1-silacyclobutane

Guidance literature:: With lithium aluminium tetrahydride; In dibutyl ether; at -5 - 5 ℃;
DOI:10.1016/S0022-328X(00)83695-5

Reference yield:

: 33687-63-7
Chlor-1-chlorpropyl-methyl-silan

: 765-33-3
1-methyl-1-silacyclobutane

: 2295-12-7
1,1-dimethylsilacyclobutane

: 18165-89-4
methyl-n-propylsilane

Guidance literature:: With potassium Sodium; In gaseous matrix; at 280 - 320 ℃; under 0.1 - 1 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/0022-328X(85)87334-4