Pentaerythritol triacrylate

Base Information

• Chemical Name: Pentaerythritol triacrylate
• CAS No.: 3524-68-3
• Deprecated CAS: 204270-19-9,85205-48-7,89900-19-6,98036-34-1,98866-06-9,162774-83-6,364365-31-1,406935-45-3,1063995-98-1,1174502-54-5,912677-42-0,1799303-67-5,1416789-49-5,2247563-81-9,1063995-98-1,1174502-54-5,162774-83-6,364365-31-1,406935-45-3,85205-48-7,89900-19-6,912677-42-0,98036-34-1,98866-06-9
• Molecular Formula: C14H18O7
• Molecular Weight: 298.293
• Hs Code.: 29161900
• European Community (EC) Number: 222-540-8
• UN Number: 3265
• UNII: PJJ1161ULF
• DSSTox Substance ID: DTXSID2025842
• Nikkaji Number: J13.724C
• Wikidata: Q26840927
• ChEMBL ID: CHEMBL1602699
• Mol file: 3524-68-3.mol

Synonyms:penta-erythritol triacrylate;pentaerythritol triacrylate;pentaerythrityl triacrylate;PETA;tetramethylolmethane triacrylate

Chemical Property of Pentaerythritol triacrylate

Chemical Property:

• Appearance/Colour: viscous yellow liquid
• Vapor Pressure: 4.08E-09mmHg at 25°C
• Melting Point: 15℃
• Refractive Index: n20/D 1.483(lit.)
• Boiling Point: 427.9 ºC at 760 mmHg
• PKA: 13.63±0.10(Predicted)
• Flash Point: 153.5 °C
• PSA: 99.13000
• Density: 1.179 g/cm³
• LogP: 0.15270
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• Water Solubility.: Immiscible with water.
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 13
• Exact Mass: 298.10525291
• Heavy Atom Count: 21
• Complexity: 365
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Pentaerythritol triacrylate technical grade ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38-43
• Safety Statements: 39

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C
• Uses: binds both covalently and irreversibly to outer cell membrane surfaces Pentaerythritol triacrylate is used in adhesives, coatings, inks, photoresists, castings, etc. cured by UV radiation; in organic synthesis. Pentaerythritol Triacrylate can lithographic printing plate precursor.

Technology Process of Pentaerythritol triacrylate

There total 5 articles about Pentaerythritol triacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Pentaerythritol (115-77-5) + acrylic acid (79-10-7) → pentaerythritol triacrylate (3524-68-3)

Guidance literature:

Pentaerythritol; acrylic acid; With IR-120 strong acid type ion exchange resin; at 100 ℃; for 0.5h;

In benzene; at 100 ℃; for 3h; Temperature;

Reference yield:

Pentaerythritol (115-77-5) + 2-methoxyethyl acrylate (3121-61-7,28628-64-0) → 2,2-bis(hydroxymethyl)-1,3-propanediyl diacrylate (53417-29-1,85614-76-2) + pentaerythritol tetraacrylate (4986-89-4) + pentaerythritol triacrylate (3524-68-3)

Guidance literature:

With zinc diacetate; oxygen; 4-methoxy-phenol; 1,8-diazabicyclo[5.4.0]undec-7-ene; at 105 - 120 ℃; for 5h; Reagent/catalyst; Overall yield = 48 %; Inert atmosphere;

Reference yield:

Pentaerythritol (115-77-5) + 2-methoxyethyl acrylate (3121-61-7,28628-64-0) → pentaerythritol tetraacrylate (4986-89-4) + pentaerythritol triacrylate (3524-68-3)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; zinc diacetate; oxygen; 4-methoxy-phenol; at 105 - 120 ℃; for 30h; under 130 - 760 Torr; Overall yield = 96 %; Inert atmosphere;

upstream raw materials:

Pentaerythritol

acrylic acid

pentaerythritol triallyl ether

2-methoxyethyl acrylate

Downstream raw materials:

pentaerythritol tris(3-(1-aziridinyl)propionate)

pentaerythritol tetraacrylate

Pentaerithrit-triacetat-acrylat

Refernces

• 1、 -. "Preparation method of pentaerythritol triacrylate". Paragraph 0029-0032; 0039-0042; 0046; 0049-0052; 0054. . Retrieved 2018/10/19.
• 2、 -. "(METH)ACRYLATE MANUFACTURING METHOD". Paragraph 0103-0104. . Retrieved 2018/05/17.