Vanadium(IV) fluoride

Base Information

• Chemical Name: Vanadium(IV) fluoride
• CAS No.: 10049-16-8
• Molecular Formula: F4V
• Molecular Weight: 126.935
• Hs Code.: 2826199090
• European Community (EC) Number: 233-171-7
• Wikidata: Q416028
• Wikipedia: Vanadium(IV) fluoride
• Mol file: 10049-16-8.mol

Synonyms:Tetrafluorovanadium;Vanadium(IV) fluoride;10049-16-8;Vanadium fluoride (VF4) (7CI,8CI,9CI);MFCD00042554;AKOS025310224;Vanadium fluoride (VF4)(7CI,8CI,9CI);L-LEUCINEBETA-NAPHTHYLAMIDEHYDROCHLORIDE;Q416028

Chemical Property of Vanadium(IV) fluoride

Chemical Property:

• Appearance/Colour: Yellow to brown liquid
• Melting Point: 325 ºC(dec.)(lit.)
• Boiling Point: 19.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 2.975 g/mL at 25 ºC(lit.)
• LogP: 1.68080
• Sensitive.: Moisture Sensitive
• Water Solubility.: Soluble in water (blue color), acetone (deep green color), and glacial acetic acid (blue-green color)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 126.937570
• Heavy Atom Count: 5
• Complexity: 19.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Vanadium(IV) fluoride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): XiT
• Hazard Codes: T,Xi
• Statements: 23/24/25-34
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: F[V](F)(F)F
• Uses: Vanadium(IV) fluoride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Technology Process of Vanadium(IV) fluoride

There total 16 articles about Vanadium(IV) fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + vanadiumtetrachloride (7632-51-1) → vanadium(IV) fluoride (10049-16-8)

Guidance literature:

In not given; under cooling;; removing of HCl and HF on oiling of soln.; heating under N2 or CO2 at 50°C;;

Reference yield:

1,1-difluoroethane (75-37-6) + vanadiumtetrachloride (7632-51-1) → vanadium(IV) fluoride (10049-16-8)

Guidance literature:

In further solvent(s); solvent: C2H5Cl; in autoclave at -78 and 60°C;;

Reference yield:

vanadium(III) chloride (7718-98-1) + fluorine (7782-41-4) → vanadium(IV) fluoride (10049-16-8)

Guidance literature:

In neat (no solvent); in 15 min at 180°C;;

upstream raw materials:

vanadium

fluorine

vanadium(III) chloride

ruthenium(V) fluoride

Downstream raw materials:

vanadium

vanadium pentafluoride

vanadium(III) fluoride

potassium hexafluoro vanadate (V)

Refernces

• 1、 Rakov,Dzhalavyan,Nikitin. "Reactions of Ruthenium Pentafluoride with Refractory Metals". . p. 1003 - 1005. Retrieved 2008/10/08.