Bismuth iodide oxide

Base Information

• Chemical Name: Bismuth iodide oxide
• CAS No.: 7787-63-5
• Molecular Formula: BiIO
• Molecular Weight: 351.884
• European Community (EC) Number: 232-126-9
• DSSTox Substance ID: DTXSID401316462
• Wikipedia: Bismuth(III) oxyiodide
• Mol file: 7787-63-5.mol

Synonyms:Bismuth iodide oxide;7787-63-5;BISMUTH OXYIODIDE;UNII-LFR582VS4X;EINECS 232-126-9;Bismuth(III) oxyiodide;LFR582VS4X;BiIO;Bismuth (III) oxy iodide;Bismuthine, iodooxo-(9CI);iodo(oxo)bismuthine;oxobismuth;hydroiodide;Bismuthine, iodooxo-;Bi-I-O;bismuth (III) oxyiodide;Bismuthine,iodooxo-(9ci);Bismuth iodide oxide (BiOI);DTXSID401316462;MFCD00015969

Chemical Property of Bismuth iodide oxide

Chemical Property:

• Appearance/Colour: White to yellowish powder
• Melting Point: fuses at red heat with partial decomposition [MER06]
• PSA: 17.07000
• Density: 7.92 g/mL at 25 °C(lit.)
• LogP: 0.76690
• Water Solubility.: insoluble H2O, alcohol, chloroform; soluble HCl; decomposed by HNO3 or alkali [MER06]
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 352.88761
• Heavy Atom Count: 3
• Complexity: 4.8

Purity/Quality:

98%Min ^*data from raw suppliers

BismuthOxyiodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O=[Bi].I
• Uses: Bismuth Oxyiodide is a catalyst that is used in the preparation of BIoI/(BiO)2CO3, a p-n junction photocatalyst.

Technology Process of Bismuth iodide oxide

There total 26 articles about Bismuth iodide oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth (III) nitrate pentahydrate + potassium iodide (7681-11-0) → bismuth oxyiodide (7787-63-5)

Guidance literature:

With acetic acid; In water; for 3.5h;

DOI:10.1021/ic400159m

Reference yield:

bismuth (III) nitrate pentahydrate + water (7732-18-5) + potassium iodide (7681-11-0) → bismuth oxyiodide (7787-63-5)

Guidance literature:

at 150 ℃; for 5h; Autoclave;

DOI:10.1002/chem.201302025

Reference yield:

bismuth titanate + lithium iodide (10377-51-2) → bismuth oxyiodide (7787-63-5)

Guidance literature:

In neat (no solvent); Bi4Ti3O12 and LiI at 300-350°C for 3-5 days, in the presence andabsence of iodine; washed with water and dried at room temp.; X-ray diffraction;

DOI:10.1006/jssc.2000.8638

upstream raw materials:

lithium iodide

bismuth(III) oxide

cadmium(II) iodide

potassium iodide

Downstream raw materials:

bismuth(III) oxide

iodine

bismuth(III) iodide

potassium iodide

Refernces

• 1、 Zhou, Yawen,Fang, Shanshan,Zhou, Man,Wang, Guanqiu,Xue, Su,Li, Zhongyu,Xu, Song,Yao, Chao. "Fabrication of novel ZnFe2O4/BiOI nanocomposites and its efficient photocatalytic activity under visible-light irradiation". . p. 353 - 361. Retrieved 2017.
• 2、 Sillen, L. G.. "". . p. 318 - 324. Retrieved 1942.
• 3、 Ye, Cui,Wu, Zhen,Ma, Keyi,Xia, Zhuohao,Pan, Jun,Wang, Minqiang,Ye, Changhui. "Ti3C2 MXene-based Schottky photocathode for enhanced photoelectrochemical sensing". . . Retrieved 2021.
• 4、 Liu, Qian,Yin, Yuanyuan,Hao, Nan,Qian, Jing,Mao, Hanping,Wang, Kun. "Self-templating synthesis of nitrogen doped graphene quantum dots/3D bismuth oxyiodine hybrid hollow microspheres with improved visible-light excited photocurrent generation: Simultaneous electron transfer acceleration and bandgap narrowing". . p. 27 - 37. Retrieved 2017.
• 5、 Boonmongkolras, Passarut,Choi, Eun-Gyu,Han, Seunghyun,Kim, Jinhyun,Kim, Kayoung,Kim, Yong Hwan,Lee, Sahng Ha,Lee, Yang Woo,Park, Chan Beum,Shin, Byungha,Trang, Nguyen Vu Thien,Wang, Ding. "Lignin-fueled photoelectrochemical platform for light-driven redox biotransformation". . p. 5151 - 5160. Retrieved 2020/08/25.