2,3,4-TRIHYDROXYBUTANOICACID

Base Information

• Chemical Name: 2,3,4-TRIHYDROXYBUTANOICACID
• CAS No.: 488-16-4
• Molecular Formula: C4H8O5
• Molecular Weight: 136.105
• Mol file: 488-16-4.mol

Synonyms:(2R,3R)-2,3,4-TRIHYDROXYBUTANOIC ACID;Butanoic acid, 2,3,4-trihydroxy-, (2R,3R)-

Chemical Property of 2,3,4-TRIHYDROXYBUTANOICACID

Chemical Property:

• PSA: 97.99000
• LogP: -2.21490

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-TRIHYDROXYBUTANOICACID

There total 74 articles about 2,3,4-TRIHYDROXYBUTANOICACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

meso-erythritol (909878-64-4,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9) + D-erythronic acid (488-16-4)

Guidance literature:

PtTl; In perchloric acid; water; for 4h; electrocatalytic reaction;

DOI:10.1051/jcp:1999157

Reference yield: 74.0%

meso-erythritol (909878-64-4,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9) + D-glyceric acid (473-81-4,600-19-1,6000-40-4,28305-26-2,118916-26-0) + D-erythronic acid (488-16-4) + D-erythrose (583-50-6)

Guidance literature:

PtTl; In perchloric acid; water; for 4h; Product distribution; electrocatalytic reaction; also on Pt and on Pt-Pb electrode; oxidation potential varied: 0.45, 0.6, 0.8 V;

DOI:10.1051/jcp:1999157

Reference yield: 35.0%

D-glucose (50-99-7) + chloroamine-T (127-65-1) → D-glyceric acid (473-81-4,600-19-1,6000-40-4,28305-26-2,118916-26-0) + D-threonic acid (20246-26-8) + D-erythronic acid (488-16-4) + arabinoic acid (488-30-2) + D-ribonic acid (642-98-8) + gluconic acid (526-95-4)

Guidance literature:

In water; at 35 ℃; Kinetics; Thermodynamic data; Mechanism; E_a; ΔH excit.; ΔG excit.; ΔS excit; add. of NaOH, var. solv. D2O;

DOI:10.1016/S0008-6215(97)00243-7

upstream raw materials:

D-Fructose

D-ribo-hexos-3-ulose

D-erythronolactone

D-glucose

Downstream raw materials:

D-erythronolactone

erythronic acid-(N'-phenyl-hydrazide)

(E)-but-2-enoic acid

3-Iodo-n-butanoic acid

Refernces

2-C-CARBOXYALDOSES AND ALDONIC ACIDS FROM CELLOBIOSE, MALTOSE, AND 4-O-METHYL-D-GLUCOSE WITH 2-ANTHRAQUINONESULFONIC ACID

10.1016/S0008-6215(00)90462-2

The research details an investigation into the oxidation of cellobiose, maltose, and 4-O-methyl-D-glucose using 2-anthraquinonesulfonic acid (AMS) in sodium hydroxide. The purpose of the study was to gain insights into the reactions of aldoses, specifically aldos-2-uloses, by subjecting these 4-O-substituted aldoses to oxidation conditions similar to those used for D-glucose. The research concluded that the oxidation products included erythronic, arabinonic, ribonic, gluconic, and mannonic acids, as well as 2-C-carboxypentoses, which were identified as a new type of product in the reaction mixture. The study also found that the nonsubstituted products of the reducing D-glucose unit consisted of formic, glycolic, 2-deoxytetronic, and 3-deoxypentonic acids, along with 2-C-carboxy-3-deoxypentoses. The chemicals used in the process included 2-anthraquinonesulfonic acid as the oxidizing agent, sodium hydroxide to maintain the reaction conditions, and various sugars as substrates for the oxidation reactions.