Triphenylstannanylium;azide

Base Information

• Chemical Name: Triphenylstannanylium;azide
• CAS No.: 1158-51-6
• Molecular Formula: C18H15 N3 Sn
• Molecular Weight: 392.047
• Mol file: 1158-51-6.mol

Synonyms:SCHEMBL1981

Chemical Property of Triphenylstannanylium;azide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 393.028800
• Heavy Atom Count: 22
• Complexity: 217

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+](C2=CC=CC=C2)C3=CC=CC=C3.[N-]=[N+]=[N-]

Technology Process of Triphenylstannanylium;azide

There total 4 articles about Triphenylstannanylium;azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.4%

(C6H5)3Sn(C5H5) + iodine(I) azide (14696-82-3) → triphenyltin azide (1158-51-6)

Guidance literature:

In tetrachloromethane; byproducts: C5H5I; (N2); heating (60°C), mixing; distn. (soln. concn., 10 mm Hg), crystn. (petroleum ether); elem. anal.;

Reference yield:

potassium azide (20762-60-1) + triphenyltin chloride (639-58-7) → triphenyltin azide (1158-51-6)

Guidance literature:

In ethanol;

DOI:10.1016/0022-328X(82)80002-8

Reference yield:

methylmercury(II) azide + Ph3SnSPh (1441-22-1) → (benzenethiolato)methylmercury(II) (17019-36-2) + triphenyltin azide (1158-51-6)

Guidance literature:

In acetone; equilibrium constant detd.; (199)Hg-NMR and (119)Sn-NMR spectroscopy;

upstream raw materials:

Ph₃SnSPh

triphenylstannylphenylselenide

iodine(I) azide

potassium azide

Downstream raw materials:

Ph₃SnN₃(2-methylimidazole)

Ph₃SnN₃(1,1,3,3-tetramethylurea)

Ph₃SnN₃(2,6-lutidine)

Ph₃SnN₃(2,4,6-collidine)

Refernces

• 1、 Dean, Philip A. W.,Vittal, Jagadese J.. "HALOGEN AND PEUDOHALOGEN SUBSTITUTION OF SOME ADAMANTANOID CHALCOGENATE CLUSTERS (2-) USING METHYLMERCURY AND TRIPHENYLTIN DERIVATIVES. A MULTINUCLEAR NUCLEAR MAGNETIC RESONANCE STUDY". . p. 2443 - 2451. Retrieved 2007/10/02.