Methyl but-2-enoate

Base Information Edit

Chemical Name:Methyl but-2-enoate
CAS No.:18707-60-3
Molecular Formula:C₅H₈O₂
Molecular Weight:100.117
Hs Code.:
DSSTox Substance ID:DTXSID30862315
Wikidata:Q72488927
Mol file:18707-60-3.mol

Synonyms:methyl but-2-enoate;methyl butenoate;methyl 3-methylacrylate;methyl-3-methylacrylate;DTXSID30862315;AKOS025243552;FT-0628329

Suppliers and Price of Methyl but-2-enoate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 15 raw suppliers

Chemical Property of Methyl but-2-enoate Edit

Chemical Property:

Vapor Pressure:0.152mmHg at 25°C
Melting Point:122-124℃
Refractive Index:n20/D 1.423(lit.)
Boiling Point:121 °C at 760 mmHg
Flash Point:4.4 °C
PSA：26.30000
Density:0.925 g/cm³
LogP:0.73550
Water Solubility.:IMMISCIBLE
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:100.052429494
Heavy Atom Count:7
Complexity:84.1

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s): F,Xi
Hazard Codes:F,Xi
Statements: 11-36/37/38
Safety Statements: 16-26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=CC(=O)OC

Technology Process of Methyl but-2-enoate

There total 39 articles about Methyl but-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.1%

: 67-56-1
methanol

: 3724-65-0
2-butenoic acid

: 623-43-8,4358-59-2,18707-60-3,130981-57-6
methyl crotonate

Guidance literature:: With thionyl chloride;

Reference yield: 70.0%

: 67-56-1
methanol

: 123-73-9,4170-30-3
crotonaldehyde

: 623-43-8,4358-59-2,18707-60-3,130981-57-6
methyl crotonate

Guidance literature:: With sodium carbonate; N,N'-diiodo-N,N'-1,2-ethanediylbis(p-toluenesulphonamide); at 20 ℃; for 18h;
DOI:10.1070/MC2005v015n05ABEH002091