Tridodecylamine

Base Information

• Chemical Name: Tridodecylamine
• CAS No.: 102-87-4
• Molecular Formula: C36H75N
• Molecular Weight: 521.998
• Hs Code.: 29211990
• European Community (EC) Number: 203-063-4
• NSC Number: 35134
• UNII: SF36T21U17
• DSSTox Substance ID: DTXSID8047056
• Nikkaji Number: J150.298K
• Wikidata: Q27289177
• Metabolomics Workbench ID: 47948
• ChEMBL ID: CHEMBL3183789
• Mol file: 102-87-4.mol

Synonyms:tri-n-dodecylamine;tri-n-dodecylamine hydrochloride

Chemical Property of Tridodecylamine

Chemical Property:

• Appearance/Colour: clear slightly yellow liquid
• Vapor Pressure: 6.41E-12mmHg at 25°C
• Melting Point: 16 °C
• Refractive Index: n20/D 1.4578(lit.)
• Boiling Point: 544.6 °C at 760 mmHg
• PKA: 9.84±0.50(Predicted)
• Flash Point: 256.6 °C
• PSA: 3.24000
• Density: 0.828 g/cm³
• LogP: 13.05110
• Storage Temp.: 2-8°C
• Water Solubility.: Not miscible or difficult to mix with water.
• XLogP3: 17
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 33
• Exact Mass: 521.58995140
• Heavy Atom Count: 37
• Complexity: 322

Purity/Quality:

99.9% ^*data from raw suppliers

Tridodecylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC
• Uses: Chemical intermediate, metal complexes. TRIDODECYLAMINE (cas# 102-87-4) is a tertiary fatty amine which has been used in the preparation of an embedded telemetry system for potentiometric sensors, and in the preparation of gemini cationic surfactant-based ionic liquids. Tridodecylamine(TDA) can be used in the following applications:Extraction of picolinic acid, citric acid, silver, mercury, selenium, zinc, cobalt, iron and succinic acid from aqueous solutions by using various organic solvents as diluents.Recovery of Remazol Red 3BS (R3BS) dye from wastewater via emulsion liquid membrane (ELM) process by using TDA as the carrier agent.Synthesis of gemini surfactant-based ionic liquids by reacting with dibromo alkanes.

Technology Process of Tridodecylamine

There total 12 articles about Tridodecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

n-Dodecylamine (124-22-1) → N,N-didodecylamine (3007-31-6) + tridodecylamine (102-87-4)

Guidance literature:

With Co₂Rh₂/C; In toluene; at 180 ℃; for 6h; under 760.051 Torr; Temperature; Time; Solvent; Autoclave; Inert atmosphere;

DOI:10.1002/adsc.201701522

Reference yield: 84.0%

undecyl cyanide (2437-25-4) → N,N-didodecylamine (3007-31-6) + tridodecylamine (102-87-4)

Guidance literature:

With hydrogen; silica gel; copper; at 160 ℃; for 2.69444h; under 33002.6 Torr; Product distribution; Rate constant; other temperatures, other catalysts;

Reference yield: 22.6%

n-Dodecylamine (124-22-1) + 1-dodecylbromide (143-15-7) → tridodecylamine (102-87-4)

Guidance literature:

With sodium carbonate; In ethanol; for 144h; Heating;

DOI:10.1021/ja00319a014

upstream raw materials:

1-Iodododecane

N,N-didodecylamine

1-chlorododecane

n-Dodecylamine

Downstream raw materials:

tri-n-dodecylmethylammonium iodide

undecyl cyanide

(E)-1-(4-(3-hydroxy-3-methylbut-1-en-1-yl)phenyl)ethan-1-one

(1E)-3-methyl-1-phenylpent-1-en-3-ol