Dodecylamine

Base Information

• Chemical Name: Dodecylamine
• CAS No.: 124-22-1
• Deprecated CAS: 126162-08-1,27177-40-8,27177-40-8
• Molecular Formula: C12H27N
• Molecular Weight: 185.353
• Hs Code.: 29211980
• European Community (EC) Number: 204-690-6,268-953-7
• ICSC Number: 1364
• UN Number: 2735
• UNII: YWY9OD6A2K
• DSSTox Substance ID: DTXSID3021984,DTXSID801022411
• Nikkaji Number: J43.184B
• Wikidata: Q21091987
• ChEMBL ID: CHEMBL109904
• Mol file: 124-22-1.mol

Synonyms:dodecylamine;dodecylamine acetate;dodecylamine hydrobromide;dodecylamine hydrochloride;dodecylamine hydrofluoride;dodecylamine nitrate;dodecylamine perchlorate;dodecylamine phosphate (1:1);dodecylamine sulfate;dodecylammonium butyrate;dodecylammonium chloride;laurylamine

Chemical Property of Dodecylamine

Chemical Property:

• Appearance/Colour: white solid
• Vapor Pressure: 64 mm Hg ( 170 °C)
• Melting Point: 28-32 ºC
• Refractive Index: 1.4421
• Boiling Point: 258.6ºC at 760 mmHg
• PKA: 10.63(at 25℃)
• Flash Point: 100.4ºC
• PSA: 26.02000
• Density: 0.804 g/cm³
• LogP: 4.56630
• Storage Temp.: Store below +30°C.
• Solubility.: water: soluble3.5g/L at 25°C
• Water Solubility.: 78 mg/L (25 ºC)
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 185.214349865
• Heavy Atom Count: 13
• Complexity: 81.2
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Dodecylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,N
• Hazard Codes: C,N
• Statements: 22-34-50/53-20/21/22-65-48/22-37-35
• Safety Statements: 26-36/37/39-45-60-61-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCCCCCCCCN
• Inhalation Risk: No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
• Effects of Short Term Exposure: The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema. The effects may be delayed. Medical observation is indicated.
• Uses: Dodecylamine was used in preparation of novel surfactant copper(II) complexes.Intercalation of dodecylamine into the layer space of kaolinite was investigated. Dodecylamine was investigated as inhibitor of mild steel hydrochloric acid corrosion. Dodecylamine was used in preparation of novel surfactant copper(II) complexes. It is used as a catalyst and template agent in the sol-gel process for the fabrication of monodispersed mesoporous bioactive glass sub-micron spheres. Dodecylamine (DDA) can be used: As a modifier in the preparation of dodecylamine incorporated sodium montmorillonite. It is used as an adsorbent for hexavalent chromium.In the synthesis of DDA-poly(aspartic acid) as a biodegradable water-soluble polymeric material.As an organic surfactant in the synthesis of Sn(IV)-containing layered double hydroxide (LDHs), which can be further used as ion exchangers, absorbents, ion conductors, and catalysts.As a complexing, reducing and capping agent in the synthesis of pentagonal silver nanowires.

Technology Process of Dodecylamine

There total 93 articles about Dodecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N-dodecylbenzamide (33140-65-7) → n-Dodecylamine (124-22-1) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With 40% potassium fluoride/alumina; for 0.0666667h; Microwave irradiation; Neat (no solvent);

DOI:10.1002/cjoc.201180383

Reference yield: 74.0%

lauric acid (143-07-7) → n-Dodecylamine (124-22-1) + n-Undecane (1120-21-4) + lauric acid amide (1120-16-7) + N,N-didodecylamine (3007-31-6) + N-dodecanoyldodecanylamide (33422-43-4)

Guidance literature:

lauric acid; With cyclopentyl methyl ether; ammonia; at 200 ℃; under 4500.45 Torr; Sealed tube; Green chemistry;

With cyclopentyl methyl ether; ammonia; hydrogen; at 200 ℃; for 6.5h; under 42004.2 Torr; Cooling with ice; Green chemistry;

DOI:10.1039/d0gc01441a

Reference yield: 39.0%

lauric acid amide (1120-16-7) → n-Dodecylamine (124-22-1) + 1-dodecyl alcohol (112-53-8)

Guidance literature:

With hydrogen; In 1,2-dimethoxyethane; at 130 ℃; for 5h; under 22502.3 Torr; Catalytic behavior; Autoclave;

upstream raw materials:

lauric acid amide

1-dodecyl alcohol

methyl n-dodecanoate

tridecanoic acid[2,6-diethyl-2,3,6-trimethyl-1-(1-phenyl-ethoxy)-piperidin-4-yl]-amide

Downstream raw materials:

2-(N-dodecylamino)ethanol

N-lauryldiethanolamine

6-dodecyl-3-oxa-6-aza-octane-1,8-diol

N-dodecylpyridin-2-amine

Refernces

• 1、 Radushev,Koltashev,Nasrtdinova,Shcherban,Chekanova,Plotnikova. "Physical and chemical properties of N-(2-hydroxyethyl)alkylamines". . p. 1475 - 1479. Retrieved 2010.
• 2、 -. "SUPPORTED HETEROGENEOUS CATALYST, PREPARATION AND USE THEREOF". Page/Page column 21. . Retrieved 2021/06/11.
• 3、 -. "MATERIALS COMPRISING CARBON-EMBEDDED COBALT NANOPARTICLES, PROCESSES FOR THEIR MANUFACTURE, AND USE AS HETEROGENEOUS CATALYSTS". Page/Page column 17; 19. . Retrieved 2021/03/13.