Sulfur chloride pentafluoride

Base Information

• Chemical Name: Sulfur chloride pentafluoride
• CAS No.: 13780-57-9
• Molecular Formula: ClF5 S
• Molecular Weight: 162.511
• European Community (EC) Number: 237-431-0
• UNII: T36C2GHD3T
• DSSTox Substance ID: DTXSID60160316
• Nikkaji Number: J134.312B
• Wikipedia: Sulfur_chloride_pentafluoride
• Wikidata: Q2336792
• Mol file: 13780-57-9.mol

Synonyms:Sulfur chloride pentafluoride;13780-57-9;SULPHUR CHLOROPENTAFLUORIDE;Chloropentafluorosulfur;Pentafluorosulfur chloride;Monochloropentafluorosulfur;chloro(pentafluoro)-lambda6-sulfane;Sulfur chloride fluorine;Sulfur chloropentafluoride;Sulphur chloride pentafluoride;SF5Cl;Sulfur monochloride pentafluoride;EINECS 237-431-0;T36C2GHD3T;ClF5S;Chlorosulfur pentafluoride;Silfur chloropentafluoride;Cl-F5-S;UNII-T36C2GHD3T;DTXSID60160316;Sulfur chloride fluoride (SClF5);chloro(pentafluoro)-$l^{6}-sulfane;MFCD00042373;AKOS040767246;LS-148159;chloranyl-pentakis(fluoranyl)-$l^{6}-sulfane;A807306;Sulfur chloride fluoride (SClF5), (OC-6-22)-;Q2336792

Chemical Property of Sulfur chloride pentafluoride

Chemical Property:

• Melting Point: -64°C
• Boiling Point: -21°C
• PSA: 25.30000
• LogP: 3.43870
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 161.9329397
• Heavy Atom Count: 7
• Complexity: 80.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sulfur chloropentafluoride 90% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 23-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Sulfur Compounds
• Canonical SMILES: FS(F)(F)(F)(F)Cl

Technology Process of Sulfur chloride pentafluoride

There total 8 articles about Sulfur chloride pentafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

sulfur (10544-50-0) + potassium fluoride (7789-23-3) + trichloroisocyanuric acid (87-90-1) → fluorosulfonyl fluoride (640723-20-2,2699-79-8,12769-73-2) + pentafluorosulfanyl chloride (13780-57-9) + thionyl fluoride (7783-42-8)

Guidance literature:

In acetonitrile; at 20 ℃; Inert atmosphere; Darkness; Sealed tube;

DOI:10.1002/anie.202103606

Reference yield: 38.0%

chlorine fluorosulfate (13997-90-5) + sulfur tetrafluoride (7783-60-0) → pentafluorosulfanyl chloride (13780-57-9) + trifluorosulfonium fluorosulfate (88548-61-2)

Guidance literature:

In neat (no solvent); ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min;

Reference yield:

dichlorodithionitronium hexafluoroarsenate (60563-08-8) + chlorine monofluoride (7790-89-8) → pentafluorosulfanyl chloride (13780-57-9) + {SF3}(1+)*{AsF6}(1-)=SF3AsF6 (30313-36-1) + difluoro-dithionitronium hexafluoroarsenate(V) + sulfur tetrafluoride (7783-60-0) + thionyl fluoride (7783-42-8)

Guidance literature:

With fluorosulfonylchloride; In not given; SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR;

DOI:10.1039/DT9830001961

upstream raw materials:

chlorine trifluoride

sulfur tetrafluoride

chlorine monofluoride

disulfur decafluoride

Downstream raw materials:

sulfuryl dichloride

fluorosulfonyl fluoride

disulfur decafluoride

pentafluorosulfur fluorosulfonate

Refernces

• 1、 Qing, Feng-Ling,Shou, Jia-Yi,Xu, Xiu-Hua. "Chemoselective Hydro(Chloro)pentafluorosulfanylation of Diazo Compounds with Pentafluorosulfanyl Chloride". supporting information. p. 15271 - 15275. Retrieved 2021/06/08.
• 2、 O'Brien, Brian A.,DesMarteau, Darryl D.. "Some reactions of sulfonyl hypohalites with sulfur tetrafluoride". . p. 644 - 648. Retrieved 2008/10/08.