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CAS No.: | 13780-57-9 |
---|---|
Name: | SULPHUR CHLOROPENTAFLUORIDE |
Article Data: | 12 |
Molecular Structure: | |
Formula: | ClF5 S |
Molecular Weight: | 162.511 |
Synonyms: | Sulfurchloride fluoride (SClF5) (6CI,7CI); Chloropentafluorosulfur;Monochloropentafluorosulfur; Pentafluorosulfur chloride; Sulfur chloridepentafluoride; Sulfur monochloride pentafluoride; Sulfur pentafluoride chloride |
Melting Point: | -64°C |
Boiling Point: | -21°C |
Hazard Symbols: | |
Risk Codes: | 23-34 |
Safety: | Poison by inhalation. An irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Cl−, F−, and SOx. See also FLUORIDES. |
PSA: | 25.30000 |
LogP: | 3.43870 |
chlorine fluorosulfate
sulfur tetrafluoride
A
pentafluorosulfanyl chloride
B
trifluorosulfonium fluorosulfate
Conditions | Yield |
---|---|
In neat (no solvent) ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min; | A 77% B 38% |
sulfur
trichloroisocyanuric acid
A
fluorosulfonyl fluoride
B
pentafluorosulfanyl chloride
C
thionyl fluoride
Conditions | Yield |
---|---|
In acetonitrile at 20℃; Inert atmosphere; Darkness; Sealed tube; | A n/a B 47% C n/a |
Conditions | Yield |
---|---|
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;; | |
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;; |
Conditions | Yield |
---|---|
In neat (no solvent) at 100 - 300°C and 3 atm;; | |
In gaseous matrix Kinetics; Irradiation (UV/VIS); photochemical reaction (Ar laser, mean power 10 mW, 450-500 nm, 100 Torr xenon as buffer gas); not isolated; IR monitoring; | |
In neat (no solvent) at 100 - 300°C and 3 atm;; |
disulfur decafluoride
pentafluorosulfanyl chloride
Conditions | Yield |
---|---|
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube at 350°C;; | |
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube under reduced pressure;; | >99 |
disulfur dichloride
F5SNCl2
A
pentafluorosulfanyl chloride
B
SF5N=SCl2
Conditions | Yield |
---|---|
In further solvent(s) Cl2S2 is placed in a FEP-trap (dry-box), evacuated and cooled to -196°C, CFCl3 is condensed into trap, mixt. is warmed to room temp., into this mixt. Fe5SNCl2 is condensed (liquid N2), cooling to -100°C, mixt. is allowed to warm; mixt. is stirred under warming to -20°C for several hours, sepn.by fractional condensation in oil vac. in cold traps at -45, -50, -196°C, react. is followed by Raman-spectroscopy; |
dichlorodithionitronium hexafluoroarsenate
chlorine monofluoride
A
pentafluorosulfanyl chloride
B
{SF3}(1+)*{AsF6}(1-)=SF3AsF6
D
sulfur tetrafluoride
E
thionyl fluoride
Conditions | Yield |
---|---|
With fluorosulfonylchloride In not given SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR; | A n/a B n/a C 0% D n/a E <1 |
Conditions | Yield |
---|---|
With trifluoroacetic acid In acetonitrile at 20℃; for 14h; Inert atmosphere; |
Conditions | Yield |
---|---|
In water at 20℃; under 1.50015 Torr; for 3.5h; UV-irradiation; | 94% |
pentafluorosulfanyl chloride
pentafuorosulfanyl hypochlorite
bis(pentafluorosulfur)oxide
Conditions | Yield |
---|---|
byproducts: SO2F2, SOF4, SF6; Irradiation (UV/VIS); irradn. for 4 h at 22°C; collection in a -196°C trap (dynamic vacuum); fractional condensation; SF5OSF5 and SF5O2SF5 in -111°C trap; mixt. heated in copper reactor at 237°C for 2.5 h;; fractional condensation yielded SF5OSF5 in a -118°C trap; further compounds (from decompn. of SF5O2SF5) in -196°C trap;; | 72% |
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Product Name: Sulphur chloropentafluoride
Synonyms:Chloropentafluorosulfur ; Monochloropentafluorosulfur ; Pentafluorosulfurchloride ; SClF5 ; SF5Cl ; Silfur chloropentafluoride ; Sulfur chloride fluoride ; Sulfur chloride fluoride (SClF5).
CAS: 13780-57-9
Molecular Formula of Sulphur chloropentafluoride (13780-57-9) : ClF5S
Molecular Weight of Sulphur chloropentafluoride (13780-57-9) : 162.51
Molecular Struture of Sulphur chloropentafluoride (13780-57-9) :
EINECS: 237-431-0
Product Categories:
Mol File: 13780-57-9.mol
Melting point: -64°C
Boiling point: -21°C
1. | ihl-rat LCLo:100 ppm/1H | BJIMAG British Journal of Industrial Medicine. 27 (1970),1. |
Hazard Codes T
Risk Statements 23-34
23: Toxic by inhalation
34: Sulphur chloropentafluoride (13780-57-9) causes burns
Safety Statements 26-36/37/39-45
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR 3308
Hazard Note Toxic
OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m3