4-trimethylsilylphenyl(triisopropoxy) titanium

Base Information

• Chemical Name: 4-trimethylsilylphenyl(triisopropoxy) titanium
• CAS No.: 1245607-83-3
• Molecular Formula: C₁₈H₃₄O₃SiTi
• Molecular Weight: 374.432
• Mol file: 1245607-83-3.mol

Synonyms:4-trimethylsilylphenyl(triisopropoxy) titanium

Chemical Property of 4-trimethylsilylphenyl(triisopropoxy) titanium

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 4-trimethylsilylphenyl(triisopropoxy) titanium

There total 1 articles about 4-trimethylsilylphenyl(triisopropoxy) titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

titanium(IV) isopropylate (546-68-9) + 1-iodo-4-(trimethylsilyl)benzene (17881-56-0) → 4-trimethylsilylphenyl(triisopropoxy) titanium (1245607-83-3)

Guidance literature:

1-iodo-4-(trimethylsilyl)benzene; In tetrahydrofuran; for 2h; Glovebox; Inert atmosphere;

titanium(IV) isopropylate; With TurboGrignard; In tetrahydrofuran; at -20 ℃; for 0.5h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.orglett.0c03673

Reference yield: 95.0%

4-trimethylsilylphenyl(triisopropoxy) titanium (1245607-83-3) + benzaldehyde (100-52-7) → (S)-phenyl 4-(trimethylsilyl)phenyl methanol

Guidance literature:

With [{(R)-H₈-BINOLate}Ti(O-i-Pr)2]x; In tetrahydrofuran; at 20 ℃; for 0.0166667h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1039/c1cc15059f

Reference yield: 94.0%

4-trimethylsilylphenyl(triisopropoxy) titanium (1245607-83-3) + benzyl bromide (100-39-0) → 4-(trimethylsilyl)diphenylmethane (17964-29-3)

Guidance literature:

With palladium diacetate; Tri(p-tolyl)phosphine; In toluene; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/adsc.201000311

upstream raw materials:

titanium(IV) isopropylate

1-iodo-4-(trimethylsilyl)benzene

Downstream raw materials:

4-(trimethylsilyl)diphenylmethane