rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl

Base Information

• Chemical Name: rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl
• CAS No.: 99666-78-1
• Molecular Formula: C₁₅H₁₂ClN₂O₃Re
• Molecular Weight: 489.932

Synonyms:

Chemical Property of rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl

Chemical Property:

Purity/Quality:

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Technology Process of rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl

There total 4 articles about rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrachloromethane (56-23-5) + Ph3SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine) (122317-08-2) + dichloromethane (75-09-2) → rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl (99666-78-1,103667-38-5) + triphenyltin chloride (639-58-7)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); N2-atmosphere; 0.5 M CCl4 in CH2Cl2, irradiation into MLCT UV-band of title compd.; not isolated, reaction followed by UV/VIS spectroscopy and quantum yielddetn.;

DOI:10.1016/s0020-1693(96)05203-6

Reference yield:

(CO)5MnRe(CO)3(bpy') (138762-33-1,138762-34-2) → dimanganese decacarbonyl (10170-69-1) + rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl (99666-78-1,103667-38-5)

Guidance literature:

With dichloromethane; In dichloromethane; Irradiation (UV/VIS); soln. of educt in CH2Cl2 irradiated with SP 2025 argon-ion laser at 514.5 nm, P(λ)=11 mW, T=293 K; not isolated; detected by IR;

DOI:10.1016/S0020-1693(00)90385-2

Reference yield:

(CO)5ReRe(CO)3(bpy') (130327-18-3) → rhenium(I) pentacarbonyl chloride (14099-01-5) + rhenium(I)(CO)3(4,4'-dinethyl-2,2'bipyridine)Cl (99666-78-1,103667-38-5)

Guidance literature:

With dichloromethane; In dichloromethane; Irradiation (UV/VIS); soln. of educt in CH2Cl2 irradiated with SP 2025 argon-ion laser at 514.5 nm, P(λ)=11 mW, T=293 K; not isolated; detected by IR;

DOI:10.1016/S0020-1693(00)90385-2

upstream raw materials:

tetrachloromethane

Ph₃SnRe(CO)3(4,4'-dimethyl-2,2'bipyridine)

dichloromethane

(CO)5MnRe(CO)3(bpy')

Downstream raw materials:

[1,3-(HCC)2-5-((4,4'-dimethyl-2,2'-bipyridine)(CO)3ReCC)C₆H₃]

fac-(N-(4-pyridyl)methyl-N,N'-dimethylaminobenzamide)(4,4'-dimethyl-2,2'-bipyridine)(CO)3Re(I)⁽¹⁺⁾

fac-(N-benzoyl-4-(aminomethyl)pyridine)(4,4'-dimethyl-2,2'-bipyridine)(CO)3Re(I)⁽¹⁺⁾

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