S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate

Base Information

• Chemical Name: S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate
• CAS No.: 139458-87-0
• Molecular Formula: C₁₃H₂₁NO₂S₃Si
• Molecular Weight: 347.599
• Mol file: 139458-87-0.mol

Synonyms:S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate

Chemical Property of S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate

There total 4 articles about S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

S,S'-Bis(trimethylsilylmethyl) N-(p-toluenesulfonyl)dithioiminocarbonate (139474-76-3) → S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate (139458-87-0)

Guidance literature:

With water; fluoride; In acetonitrile;

DOI:10.1016/S0040-4039(00)77680-5

Reference yield: 71.0%

S-methyl N-(p-toluenesulfonyl)dithioiminocarbonate (6503-22-6) + Chloromethyltrimethylsilane (2344-80-1) → S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate (139458-87-0)

Guidance literature:

With sodium hydroxide; sodium iodide; In ethanol; for 20h; Heating;

DOI:10.1016/S0040-4039(00)77680-5 DOI:10.1248/cpb.43.1425

Reference yield: 20.0%

trimethylsilanyl-methanethiol (18165-76-9) + N-[bis(methylthio)methylene]-p-toluenesulfonamide (2651-15-2) → S-Methyl-S'-trimethylsilylmethyl N-(p-toluenesulfonyl)dithioiminocarbonate (139458-87-0) + S,S'-Bis(trimethylsilylmethyl) N-(p-toluenesulfonyl)dithioiminocarbonate (139474-76-3)

Guidance literature:

In methanol; Heating;

DOI:10.1016/S0040-4039(00)77680-5

upstream raw materials:

trimethylsilanyl-methanethiol

N-[bis(methylthio)methylene]-p-toluenesulfonamide

S,S'-Bis(trimethylsilylmethyl) N-(p-toluenesulfonyl)dithioiminocarbonate

S-methyl N-(p-toluenesulfonyl)dithioiminocarbonate

Downstream raw materials:

4-ethenylbenzonitrile

4-nitrostyrene

2-(2,6-dichlorophenyl)thiirane

2-(4-phenylphenyl)thiirane