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| CAS No.: | 72287-26-4 |
|---|---|
| Name: | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) |
| Molecular Structure: | |
|
|
|
| Formula: | C34H28Cl2FeP2Pd |
| Molecular Weight: | 851.095 |
| Synonyms: | Palladium,[1,1'-bis(diphenylphosphino)ferrocene-P,P']dichloro-, (SP-4-2)-;Ferrocene,1,1'-bis(diphenylphosphino)-, palladium complex;(Bis(h5-(diphenylphosphino)cyclopentadienyl)iron)dichloropalladium;1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II);1,1'-Bis(diphenylphosphino)ferrocenepalladium dichloride;Dichloro(diphenylphosphinoferrocene)palladium;Dichloro[1,1'-bis(diphenylphosphine)ferrocene]palladium(II);Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium;Pd(dppf)Cl2;PdCl2(dppf);[1,1'-Bis(diphenylphosphino-kP)ferrocene]dichloropalladium; |
| EINECS: | 460-040-3 |
| Melting Point: | 275-280 °C(lit.) |
| Hazard Symbols: |
Xn, Xi
|
| Risk Codes: | 20/21/22-36/37/38-40 |
| Safety: | 23-24/25-26-36/37 |
| PSA: | 27.18000 |
| LogP: | 7.76790 |

1,1'-bis-(diphenylphosphino)ferrocene


bis(acetonitrile)palladium(II) chloride


1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

| Conditions | Yield |
|---|---|
| In benzene stirred at room temp. for 12 h; ppt. filtered, washed with benzene, dried in vac., recrystn. (CHCl3); elem. anal.; | 97% |

1,1'-bis-(diphenylphosphino)ferrocene


chloroform


1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

| Conditions | Yield |
|---|---|
| for 0.5h; Heating; |



1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone


1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


dichloromethane

| Conditions | Yield |
|---|---|
| Stage #1: 1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol | 71% |



4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide


1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


dichloromethane

| Conditions | Yield |
|---|---|
| Stage #1: 4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol | 64% |



5-nitrofurfural 4-methyl-thiosemicarbazone


1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


dichloromethane

| Conditions | Yield |
|---|---|
| Stage #1: 5-nitrofurfural 4-methyl-thiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol | 62% |



1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


dichloromethane


5-nitro-furfural thiosemicarbazone

| Conditions | Yield |
|---|---|
| Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; 5-nitro-furfural thiosemicarbazone In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol | 61% |



1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


Sodium salt of tropolone

| Conditions | Yield |
|---|---|
| Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; Sodium salt of tropolone In methanol at 20℃; for 24h; Stage #2: sodium hexaflorophosphate In methanol for 24h; | 49% |



1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


sodium salt of 4-isopropyltropolone

| Conditions | Yield |
|---|---|
| Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; sodium salt of 4-isopropyltropolone In methanol for 6h; Reflux; Stage #2: sodium hexaflorophosphate In methanol for 24h; | 44% |



1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


nitroxoline

| Conditions | Yield |
|---|---|
| Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; nitroxoline With triethylamine In methanol for 5h; Reflux; Stage #2: sodium hexaflorophosphate In methanol for 0.25h; | 41% |



1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct


chloroxine

| Conditions | Yield |
|---|---|
| Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; chloroxine With triethylamine In methanol at 20℃; for 15 - 24h; Stage #2: sodium hexaflorophosphate In methanol for 0.25h; | 37% |

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The Molecular Structure of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (CAS NO.72287-26-4):

Empirical Formula: C34H28Cl2FeP2Pd
Molecular Weight: 731.7046
Nominal Mass: 730 Da
Average Mass: 731.7046 Da
Monoisotopic Mass: 729.942753 Da
Melting Point: 275-280 °C(lit.)
Product Categories: Metal Compounds;pharmacetical;API intermediates;Catalysts-Ligands;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Metallocenes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium
Hazard Codes:
Xn
Xi
Risk Statements: 20/21/22-36/37/38-40
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed
R36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements: 23-24/25-26-36/37
S23:Do not breathe vapour
S24/25:Avoid contact with skin and eyes
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37:Wear suitable protective clothing and gloves
Hazard Note: Irritant
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (CAS NO.72287-26-4) is also called as1,1-Bis(diphenylphosphino)ferrocenedichloropalladium(ii) ; 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ; 1,1'-Bis(diphenylphosphino)ferrocenepalladium(ii) dichloride ; Pdcl2(dppf);dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (ii) dichloromethane add ; [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium ; (ii)Dichloromethane adduct .