ETHYL-1-13C ALCOHOL

Base Information

• Chemical Name: ETHYL-1-13C ALCOHOL
• CAS No.: 14742-23-5
• Molecular Formula: C2H6O
• Molecular Weight: 47.058
• Mol file: 14742-23-5.mol

Synonyms:Ethyl-1-13Calcohol (6CI,7CI,8CI);

Chemical Property of ETHYL-1-13C ALCOHOL

Chemical Property:

• Melting Point: -130 °C(lit.)
• Refractive Index: n20/D 1.362(lit.)
• Boiling Point: 78 °C(lit.)
• Flash Point: 48 °F
• PSA: 20.23000
• Density: 0.78 g/cm³
• LogP: -0.00140

Purity/Quality:

98%Min ^*data from raw suppliers

Ethanol-1-13C 99 atom % ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11
• Safety Statements: 7-16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL-1-13C ALCOHOL

There total 7 articles about ETHYL-1-13C ALCOHOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-Phenylphenacyl <1-13C>Acetate (73377-65-8) → ethanol-1-13C (14742-23-5)

Guidance literature:

With lithium aluminium tetrahydride; In diethylene glycol dimethyl ether; for 4h; Ambient temperature;

DOI:10.1021/ja00389a060

Reference yield:

[1-13C]-acetic acid (1563-79-7) → ethanol-1-13C (14742-23-5)

Guidance literature:

With lithium aluminium tetrahydride;

DOI:10.1021/ja00336a022

Reference yield:

Dimethyl ether (115-10-6,157621-61-9) + carbon dioxide (1111-72-4) → methanol (67-56-1) + ethanol-1-13C (14742-23-5) + [13C]Carbon monoxide (1641-69-6)

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; hydrogen; cobalt(II) iodide; lithium iodide; at 180 ℃; for 12h; under 60006 Torr;

DOI:10.1039/c7gc02807e

upstream raw materials:

methyl magnesium iodide

carbon dioxide

[1-13C]-acetic acid

[1-13C]acetyl chloride

Downstream raw materials:

carbon monoxide-¹³C-¹⁸O

carbon dioxide-¹³C-¹⁸O₁

methane

ethane-¹³C₁

Refernces

• 1、 Qian, Qingli,Cui, Meng,Zhang, Jingjing,Xiang, Junfeng,Song, Jinliang,Yang, Guanying,Han, Buxing. "Synthesis of ethanol via a reaction of dimethyl ether with CO2 and H2". supporting information. p. 206 - 213. Retrieved 2018/01/12.
• 2、 Bouchoux, Guy,Tortajada, Jeanine,Dagaut, Jacques,Fillaux, Joelle. "Unimolecular Dissociations of the +. Metastable Ion". . p. 451 - 457. Retrieved 2007/10/02.